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raketka [301]
2 years ago
5

A rigid tank contains 1 kg of oxygen (O2) at p1 = 35 bar, T1 = 180 K. The gas is cooled until the temperature drops to 150 K. De

termine the volume of the tank, in m3, and the final pressure, in bar, using the:
(a) ideal gas equation of state.
(b) Redlich–Kwong equation.
Engineering
1 answer:
andreyandreev [35.5K]2 years ago
3 0

Answer:

a. Volume = 13.36 x 10^-3 m³ Pressure = 29.17 bar  b. Volume = 14.06 x 10^-3 m³ Pressure = 22.5 bar

Explanation:

Mass of O₂ = 1kg, Pressure (P1) = 35bar, T1= 180K, T2= 150k Molecular weight of O₂ = 32kg/Kmol

Volume of tank and final pressure using a)Ideal Gas Equation and b) Redlich - Kwong Equation

a. PV=mRT

V = {1 x (8314/32) x 180}/(35 x 10⁵) = 13.36 x 10^-3

Since it is a rigid tank the volume of the tank must remain constant and hnece we can say

T2/T1 = P2/P1, solving for P2

P2 = (150/180) x 35 = 29.17bar

b. P1 = {RT1/(v1-b)} - {a/v1(v1+b)(√T1)}

where R, a and b are constants with the values of, R = 0.08314bar.m³/kmol.K, a = 17.22(m³/kmol)√k, b = 0.02197m³/kmol

solving for v1

35 = {(0.08314 x 180)/(v1 - 0.02197)} - {17.22/(v1)(v1 + 0.02197)(√180)}

35 = {14.96542/(v1-0.02197)} - {1.2835/v1(v1 + 0.02197)}

Using Trial method to find v1

for v1 = 0.5

Right hand side becomes =  {14.96542/(0.5-0.02197)} - {1.2835/0.5(0.5 + 0.02197)} = 31.30 ≠ Left hand side

for v1 = 0.4

Right hand side becomes =  {14.96542/(0.4-0.02197)} - {1.2835/0.4(0.4 + 0.02197)} = 39.58 ≠ Left hand side

for v1 = 0.45

Right hand side becomes =  {14.96542/(0.45-0.02197)} - {1.2835/0.45(0.45 + 0.02197)} = 34.96 ≅ 35

Specific Volume = 35 m³/kmol

V = m x Vspecific/M = (1 x 0.45)/32 = 14.06 x 10^-3 m³

For Pressure P2, we know that v2= v1

P2 = {RT2/(v2-b)} - {a/v2(v2+b)(√T2)} = {(0.08314 x 150)/(0.45 - 0.02197)} - {17.22/(0.45)(0.45 + 0.02197)(√150)} = 22.5 bar

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Air modeled as an ideal gas enters a turbine operating at steady state at 1040 K, 278 kPa and exits at 120 kPa. The mass flow ra
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b) e=91.3 %

Explanation:

A) First, let's write the energy balance:

W=m*(h_{2}-h_{1})\\W=m*Cp*(T_{2}-T_{1})  (The enthalpy of an ideal gas is just function of the temperature, not the pressure).

The Cp of air is: 1.004 \frac{kJ}{kgK} And its specific R constant is 0.287 \frac{kJ}{kgK}.

The only unknown from the energy balance is T_{2}, so it is possible to calculate it. The power must be negative because the work is done by the fluid, so the energy is going out from it.

T_{2}=T_{1}+\frac{W}{mCp}=1040K-\frac{1120kW}{5.5\frac{kg}{s}*1.004\frac{kJ}{kgk}} \\T_{2}=837.2K

B) The isentropic efficiency (e) is defined as:

e=\frac{h_{2}-h_{1}}{h_{2s}-h_{1}}

Where {h_{2s} is the isentropic enthalpy at the exit of the turbine for the isentropic process. The only missing in the last equation is that variable, because h_{2}-h_{1} can be obtained from the energy balance  \frac{W}{m}=h_{2}-h_{1}

h_{2}-h_{1}=\frac{-1120kW}{5.5\frac{kg}{s}}=-203.64\frac{kJ}{kg}

An entropy change for an ideal gas with  constant Cp is given by:

s_{2}-s_{1}=Cpln(\frac{T_{2}}{T_{1}})-Rln(\frac{P_{2}}{P_{1}})

You can review its deduction on van Wylen 6 Edition, section 8.10.

For the isentropic process the equation is:

0=Cpln(\frac{T_{2}}{T_{1}})-Rln(\frac{P_{2}}{P_{1}})\\Rln(\frac{P_{2}}{P_{1}})=Cpln(\frac{T_{2}}{T_{1}})

Applying logarithm properties:

ln((\frac{P_{2}}{P_{1}})^{R} )=ln((\frac{T_{2}}{T_{1}})^{Cp} )\\(\frac{P_{2}}{P_{1}})^{R}=(\frac{T_{2}}{T_{1}})^{Cp}\\(\frac{P_{2}}{P_{1}})^{R/Cp}=(\frac{T_{2}}{T_{1}})\\T_{2}=T_{1}(\frac{P_{2}}{P_{1}})^{R/Cp}

Then,

T_{2}=1040K(\frac{120kPa}{278kPa})^{0.287/1.004}=817.96K

So, now it is possible to calculate h_{2s}-h_{1}:

h_{2s}-h_{1}}=Cp(T_{2s}-T_{1}})=1.004\frac{kJ}{kgK}*(817.96K-1040K)=-222.92\frac{kJ}{kg}

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e=\frac{h_{2}-h_{1}}{h_{2s}-h_{1}}=\frac{-203.64\frac{kJ}{kg}}{-222.92\frac{kJ}{kg}}\\e=0.913=91.3 %

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