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Anika [276]
3 years ago
15

Consider the following mechanism: (1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast] (2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [s

low] (3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast] (a) What is the overall equation? Select the single best answer. ClO−(aq) + I−(aq) → IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) → IO−(aq) + Cl−(aq) (b) Identify the intermediate(s), if any. Select the single best answer. No intermediates Cl−, OH−, I−, ClO−, IO− HClO, OH−, HIO HClO, OH−, HIO, H2O (c) What are the molecularity and the rate law for each step? Select the single best answers. (1): bimolecular unimolecular termolecular rate = k1([HClO][OH−])/([HClO][OH−]) k1[HClO][OH−] k1[ClO−][H2O] (2): bimolecular unimolecular termolecular rate = k2[HIO][Cl−] k2([HIO][Cl−])/([I−][HClO]) k2[I−][HClO] (3): bimolecular unimolecular termolecular rate = k3[OH−][HIO] k3([H2O][IO−])/([OH−][HIO]) k3[H2O][IO−] (d) Is the mechanism consistent with the actual rate law: rate = k[ClO−][I−]? no yes
Chemistry
1 answer:
mash [69]3 years ago
8 0

Answer:

1. The overall equation is ClO-(aq)+I-(aq) → Cl-(aq)+IO-(aq)

2. The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3. The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. No,

The rate depends on [OH-], so it's not consistent with the actual rate law

Explanation:

1

Given

(1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

(2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

(3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Add up the three equations

ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Remove all common terms {H2O(l) + I-(aq) +HClO(aq) +OH-(aq) +HIO(aq) => HClO(aq) + OH-(aq) + HIO(aq)

+H2O(l)}

We're left with

ClO-(aq) + I-(aq) => Cl-(aq) + IO-(aq)

2.

There are intermediates generated but they are not visible in the overall equation.

The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3.

The three steps are bimolecular.

The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. Let K represents equilibrium constant

At step 1,

K1 = [HClO][OH-]/[ClO-]

Simplify;

K1 [ClO-]= [HClO][OH-]

K1[ClO-]/[OH-] = [HClO]

Determine the rate at step 2

= k2[I-][HClO]

= K1k2[I-][ClO-]/[OH-]

= k[ClO-][I-]/[OH-]

The answer is no

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3 years ago
A disk of radius 2.0 cm has a surface charge density of 6.3 μC/m2 on its upper face. What is the magnitude of the electric field
maksim [4K]

Answer:

the electric field at Z = 12 cm is E =   9.68 × 10³ N/C = 9.68 kN/C

Explanation:

Given: radius of disk, R = 2.0 cm = 2 × 10⁻² cm, surface charge density,σ = 6.3 μC/m² = 6.3 × 10⁻⁶ C/m², distance on central axis, z = 12 cm = 12 × 10⁻² cm.

The electric field, E at a point on the central axis of a charged disk is given by E = σ/ε₀(1 - \frac{z}{\sqrt{z^{2} + R^{2} }  })

Substituting the values into the equation, it becomes

E = σ/ε₀(1 - \frac{z}{\sqrt{z^{2} + R^{2} }  }) = 6.3 × 10⁻⁶/8.854 × 10⁻¹²(1 - \frac{0.12}{\sqrt{0.12^{2} + 0.02^{2} } }) = 7.12 × 10⁵(1 - \frac{0.12}{0.1216}) = 7.12 × 10⁵(1 - 0.9864) = 7.12 × 10⁵ × 0.0136 = 0.0968 × 10⁵ = 9.68 × 10³ N/C = 9.68 kN/C

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7 0
3 years ago
The combustion of 0.570 g of benzoic acid (ΔHcomb = 3,228 kJ/mol; MW = 122.12 g/mol) in a bomb calorimeter increased the tempera
torisob [31]

Answer:

The temperature change from the combustion of the glucose is 6.097°C.

Explanation:

Benzoic acid;

Enthaply of combustion of benzoic acid = 3,228 kJ/mol

Mass of benzoic acid = 0.570 g

Moles of benzoic acid = \frac{0.570 g}{122.12 g/mol}=0.004667 mol

Energy released by 0.004667 moles of benzoic acid on combustion:

Q=3,228 kJ/mol \times 0.004667 mol=15.0668 kJ=15,066.8 J

Heat capacity of the calorimeter = C

Change in temperature of the calorimeter = ΔT = 2.053°C

Q=C\times \Delta T

15,066.8 J=C\times 2.053^oC

C=7,338.92 J/^oC

Glucose:

Enthaply of combustion of glucose= 2,780 kJ/mol.

Mass of glucose=2.900 g

Moles of glucose = \frac{2.900 g}{180.16 g/mol}=0.016097 mol

Energy released by the 0.016097 moles of calorimeter  combustion:

Q'=2,780 kJ/mol \times 0.016097 mol=44.7491 kJ=44,749.1 J

Heat capacity of the calorimeter = C (calculated above)

Change in temperature of the calorimeter on combustion of glucose = ΔT'

Q'=C\times \Delta T'

44,749.1 J=7,338.92 J/^oC\times \Delta T'

\Delta T'=6.097^oC

The temperature change from the combustion of the glucose is 6.097°C.

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