1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Anika [276]
3 years ago
15

Consider the following mechanism: (1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast] (2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [s

low] (3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast] (a) What is the overall equation? Select the single best answer. ClO−(aq) + I−(aq) → IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) → IO−(aq) + Cl−(aq) (b) Identify the intermediate(s), if any. Select the single best answer. No intermediates Cl−, OH−, I−, ClO−, IO− HClO, OH−, HIO HClO, OH−, HIO, H2O (c) What are the molecularity and the rate law for each step? Select the single best answers. (1): bimolecular unimolecular termolecular rate = k1([HClO][OH−])/([HClO][OH−]) k1[HClO][OH−] k1[ClO−][H2O] (2): bimolecular unimolecular termolecular rate = k2[HIO][Cl−] k2([HIO][Cl−])/([I−][HClO]) k2[I−][HClO] (3): bimolecular unimolecular termolecular rate = k3[OH−][HIO] k3([H2O][IO−])/([OH−][HIO]) k3[H2O][IO−] (d) Is the mechanism consistent with the actual rate law: rate = k[ClO−][I−]? no yes
Chemistry
1 answer:
mash [69]3 years ago
8 0

Answer:

1. The overall equation is ClO-(aq)+I-(aq) → Cl-(aq)+IO-(aq)

2. The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3. The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. No,

The rate depends on [OH-], so it's not consistent with the actual rate law

Explanation:

1

Given

(1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

(2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

(3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Add up the three equations

ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Remove all common terms {H2O(l) + I-(aq) +HClO(aq) +OH-(aq) +HIO(aq) => HClO(aq) + OH-(aq) + HIO(aq)

+H2O(l)}

We're left with

ClO-(aq) + I-(aq) => Cl-(aq) + IO-(aq)

2.

There are intermediates generated but they are not visible in the overall equation.

The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3.

The three steps are bimolecular.

The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. Let K represents equilibrium constant

At step 1,

K1 = [HClO][OH-]/[ClO-]

Simplify;

K1 [ClO-]= [HClO][OH-]

K1[ClO-]/[OH-] = [HClO]

Determine the rate at step 2

= k2[I-][HClO]

= K1k2[I-][ClO-]/[OH-]

= k[ClO-][I-]/[OH-]

The answer is no

You might be interested in
It all adds up worksheet
Komok [63]
Atomic number and the number of protons are the same...
Neutrons = Mass number - number of protons
Electrons are same # unless there is a charge 
The whole number you see on the periodic table is the atomic number of the element which is also same as the number of protons

1) carbon - 14  ;  Mass number = 14 , Protons = 6 , Neutrons = 14 - 6 = 8 
                                Electrons = 6 

2) Lead - 208  ; Mass # = 208 , Protons = 82 , Neutrons = 208 - 82 = 126
                          Electrons = 82

3) Uranium - 239 ; Mass # = 239  , Protons  =  92,Neutrons = 239 - 92 = 147
                                 Electrons =  92

4) Uranium - 238  ; Mass # = 238 , Protons = 92 , Neutrons = 238 - 92 = 146
                                   
Electrons = 92 

5) Tin - 118  ; Mass # = 118 , Protons = 50 , Neutrons = 118 - 50 = 68
                         Electrons = 50
8 0
3 years ago
Scientist can use the of minerals to tell them apart A.sound B.length C.size D.color
ipn [44]

Answer:

color

Explanation:

Scientists can use the color of minerals to tell them apart.

7 0
3 years ago
The PH of a solution of Hcl is 2.find out the amount of acid present in a litre of the solution ​
Scrat [10]

Answer:

The solution is 10^-2 or 0.01M in HCl.

Explanation:

meaning of pH is "power of hydrogen".

what is the molar concentration of a HCl solution with pH=2?

Let say pH=2

[H+]=10^-2M

HCL is a strong acid that dissociates completely:

[H+]=[HCL]

Therefore solution is 10^-2 or 0.01M in HCL.

5 0
3 years ago
You have two sealed jars of water at the same temperature. In the first jar there is a large amount of water. In the second jar
melisa1 [442]

since both the jars are kept at the same temperature the vapor pressure will be same in both the cases.


3 0
3 years ago
Which is a factor in determining the average atomic mass of an element?
kvasek [131]
The factor in determining the average atomic mass of an element is: 
B or 2 relative abundance of each isotope because the by looking at how many protons , electrons and neutrons the most isotope is of the element has relative abundance. 
7 0
3 years ago
Read 2 more answers
Other questions:
  • How do hydroelectric dams emit greenhouse gases like methane without burning any fossil fuels?
    10·1 answer
  • If an atom gains or loses an electron it tends to become what?
    13·2 answers
  • What form of oxygen is not toxic to microorganism is it oh-?
    13·1 answer
  • What is a common property of metals? a) insulates from electricity b) conducts electricity c) has very little reactivity' d) is
    7·2 answers
  • Please help me quickly with all questions!
    13·2 answers
  • Which layers of the earths are common to both the compostitional and mechanical descriptions
    8·1 answer
  • Which of the following objects is NOT a part of our solar system? A. the North Star B. the dwarf planet Pluto C. the asteroid be
    8·2 answers
  • What is acceleration deus to gravity​
    10·1 answer
  • Explain why crushed garlic has more flavor when put in food than a whole clove of garlic.
    9·1 answer
  • One quarter of chlorine is chlorine-37 and the rest is Chlorine-35. Calculate the average mass of chlorine
    15·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!