1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Anika [276]
3 years ago
15

Consider the following mechanism: (1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast] (2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [s

low] (3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast] (a) What is the overall equation? Select the single best answer. ClO−(aq) + I−(aq) → IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + Cl−(aq) ClO−(aq) + I−(aq) ⇌ IO−(aq) + H2O(l) + Cl−(aq) ClO−(aq) + I−(aq) → IO−(aq) + Cl−(aq) (b) Identify the intermediate(s), if any. Select the single best answer. No intermediates Cl−, OH−, I−, ClO−, IO− HClO, OH−, HIO HClO, OH−, HIO, H2O (c) What are the molecularity and the rate law for each step? Select the single best answers. (1): bimolecular unimolecular termolecular rate = k1([HClO][OH−])/([HClO][OH−]) k1[HClO][OH−] k1[ClO−][H2O] (2): bimolecular unimolecular termolecular rate = k2[HIO][Cl−] k2([HIO][Cl−])/([I−][HClO]) k2[I−][HClO] (3): bimolecular unimolecular termolecular rate = k3[OH−][HIO] k3([H2O][IO−])/([OH−][HIO]) k3[H2O][IO−] (d) Is the mechanism consistent with the actual rate law: rate = k[ClO−][I−]? no yes
Chemistry
1 answer:
mash [69]3 years ago
8 0

Answer:

1. The overall equation is ClO-(aq)+I-(aq) → Cl-(aq)+IO-(aq)

2. The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3. The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. No,

The rate depends on [OH-], so it's not consistent with the actual rate law

Explanation:

1

Given

(1) ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

(2) I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

(3) OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Add up the three equations

ClO−(aq) + H2O(l) ⇌ HClO(aq) + OH−(aq) [fast]

I−(aq) + HClO(aq) → HIO(aq) + Cl−(aq) [slow]

OH−(aq) + HIO(aq) → H2O(l) + IO−(aq) [fast]

Remove all common terms {H2O(l) + I-(aq) +HClO(aq) +OH-(aq) +HIO(aq) => HClO(aq) + OH-(aq) + HIO(aq)

+H2O(l)}

We're left with

ClO-(aq) + I-(aq) => Cl-(aq) + IO-(aq)

2.

There are intermediates generated but they are not visible in the overall equation.

The intermediates include: HClO(aq), OH-(aq) and HIO(aq)

3.

The three steps are bimolecular.

The rates are k[ClO-][H2O], k[I-][HClO] and k[OH-][HIO]

4. Let K represents equilibrium constant

At step 1,

K1 = [HClO][OH-]/[ClO-]

Simplify;

K1 [ClO-]= [HClO][OH-]

K1[ClO-]/[OH-] = [HClO]

Determine the rate at step 2

= k2[I-][HClO]

= K1k2[I-][ClO-]/[OH-]

= k[ClO-][I-]/[OH-]

The answer is no

You might be interested in
Name two chemical used to disinfect water
dmitriy555 [2]

Answer:

chlorine and I think maybe sulphur. but check the internet

4 0
3 years ago
Read 2 more answers
Help Me Please Thank You
NISA [10]
The Gulf Stream, warm current in the Atlantic
3 0
2 years ago
Read 2 more answers
Any one can you help me with this from 8 to 10 all plz HURRY TO ME
Makovka662 [10]
I’ll get back to u on this
8 0
3 years ago
Read 2 more answers
A. How many moles of H2 are produced from two<br> moles of CH4 ?
Nina [5.8K]
Every mole of CH4 used, three moles of H2 are produced, so 2 moles of CH4, would be 6 moles of H2 produced
8 0
2 years ago
Calculate the volume of a 0.5M solution containing 20g of NaOH
Tju [1.3M]

Answer:

1L

Explanation:

First, let us calculate the number of mole present in 20g of NaOH. This is illustrated below:

Mass = 20g

Molar Mass of NaOH = 23 + 16 + 1 = 40g/mol

Number of mole =?

Number of mole = Mass /Molar Mass

Number of mole of NaOH = 20/40 = 0.5mol

From the question given, we obtained the following data:

Molarity = 0.5M

Mole = 0.5mole

Volume =?

Molarity = mole /Volume

Volume = mole /Molarity

Volume = 0.5/0.5

Volume = 1L

6 0
3 years ago
Read 2 more answers
Other questions:
  • You work in the special effects department of a movie studio. You are currently working on a superhero movie where the hero is v
    6·1 answer
  • A mixture containing nitrogen and hydrogen weighs 3.49 g and occupies a volume of 7.45 L at 305 K and 1.03 atm. Calculate the ma
    6·1 answer
  • if 12 molecules of methane reacted with plenty of oxygen, we should expect to produce____ molecules of car on dioxide and _____
    14·1 answer
  • How do scientists test their ideas?
    6·2 answers
  • Describe the method for taking an accurate measurement by using a measuring tool.
    9·1 answer
  • A 1.0mol sample of which of the following compounds has the greatest mass?
    9·1 answer
  • How many atoms are in 13.0 g Sr
    13·1 answer
  • Which of the following statements is true?
    6·1 answer
  • Organic compounds and their uses​
    8·1 answer
  • Uranium and radium are found in many rocky soils throughout the world. Both undergo radioactive decay, and one of the products i
    7·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!