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zlopas [31]
2 years ago
10

In vacuum, the speed of light is c= 2.998 x 108m/s. However, the speed generally decreases when light travels through media othe

r than vacuum. Then, the speed is approximately c divided by a quantity called the medium's refractive index (7). In which of the following, would the frequency of 210nm-light be the lowest? (c = 2v) (1) H2, n = 1.0001 (2) CCl4, n = 1.461 (3) H20, n = 1.3330 (4) silicone oil, n = 1.520 (5) diamond, n = 2.419
Chemistry
1 answer:
Kaylis [27]2 years ago
4 0

Answer:

Light of wavelength 200 nm will have lowest frequency in while traveling through diamond.

Explanation:

Speed of the light in vacuum = c

Relation between speed of light , wavelength (λ) and frequency (ν);

\nu =\frac{c}{\lambda }

Speed of light in a medium = c' = c/n

\nu =\frac{c'}{\lambda }=\frac{c}{n\times \lambda }...[1]

Where : n = refractive index of a medium

So, the medium with greater value of refractive index lower the speed of light to greater extent.

From [1] , we can see that frequency of light is inversely proportional to the refractive index of the medium :

\nu \propto \frac{1}{n}

This means that higher the value of refractive index lower will be the value of frequency of light in that medium or vice-versa.

According to question, light of wavelength 200 nm will have lowest frequency in while traveling through diamond because refractive index of diamond out of the given mediums is greatest.

Increasing order of refractive indices:

H_2

Decreasing order of frequency of light 210 nm in these medium :

H_2>H_2O>CCL_4>\text{Silicon oil}> Diamond

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The reaction rate of equation (1) is given by:

rate = k*[O_{3}][NO]     (2)

<u>We have:</u>

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rate = k*[O_{3}]_{0}[NO]_{0} = 3.91 \cdot 10^{6} M^{-1}s^{-1}*2.35\cdot 10^{-6} M*7.74 \cdot 10^{-5} M = 7.11 \cdot 10^{-4} M/s  

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t = 1 h

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\frac{\Delta[NO_{2}]}{\Delta t} = rate

\frac{\Delta[NO_{2}]}{\Delta t} = 7.11 \cdot 10^{-4} M/s*\frac{3600 s}{1 h} = 2.56 mol.L^{-1}.h{-1}

Hence, the number of moles of NO₂(g) produced per hour per liter of air is 2.56 mol.L⁻¹.h⁻¹

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