<u>Answer:</u> The molar mass of unknown triprotic acid is 97.66 g/mol
<u>Explanation:</u>
To calculate the molarity of acid, we use the equation given by neutralization reaction:

where,
are the n-factor, molarity and volume of triprotic acid
are the n-factor, molarity and volume of base which is NaOH.
We are given:

Putting values in above equation, we get:

To calculate the molecular mass of solute, we use the equation used to calculate the molarity of solution:

We are given:
Molarity of solution = 0.0077 M
Given mass of triprotic acid = 0.188 g
Volume of solution = 250 mL
Putting values in above equation, we get:

Hence, the molar mass of unknown triprotic acid is 97.66 g/mol
Answer:
The law of floatation is applied in all vessels which travel by waterways that include ships, submarines and ferry boats. It is also applied in some vessels which travel by air ways such as hot air balloon and air ship. Balloons of different colors and shapes are filled with lighter gas so that will float in air.
Energy is distributed not just in translational KE, but also in rotation, vibration and also distributed in electronic energy levels (if input great enough, bond breaks).
All four forms of energy are quantised and the quanta ‘gap’ differences increases from trans. KE ==> electronic.
Entropy (S) and energy distribution: The energy is distributed amongst the energy levels in the particles to maximise their entropy.
Entropy is a measure of both the way the particles are arranged AND the ways the quanta of energy can be arranged.
We can apply ΔSθsys/surr/tot ideas to chemical changes to test feasibility of a reaction:
ΔSθtot = ΔSθsys + ΔSθsurr
ΔSθtot must be >=0 for a chemical change to be feasible.
For example: CaCO3(s) ==> CaO(s) + CO2(g)
ΔSθsys = ΣSθproducts – ΣSθreactants
ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s)
ΔSθsurr is –ΔHθ/T(K) and ΔH is very endothermic (very +ve),
Now ΔSθsys is approximately constant with temperature and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall.
But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800oCΔSθtot becomes plus overall (and ΔGθ becomes negative), so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.
CaCO3(s) ==> CaO(s) + CO2(g) ΔHθ = +179 kJ mol–1 (very endothermic)
This important industrial reaction for converting limestone (calcium carbonate) to lime (calcium oxide) has to be performed at high temperatures in a specially designed limekiln – which these days, basically consists of a huge rotating angled ceramic lined steel tube in which a mixture of limestone plus coal/coke/oil/gas? is fed in at one end and lime collected at the lower end. The mixture is ignited and excess air blasted through to burn the coal/coke and maintain a high operating temperature.
ΔSθsys = ΣSθproducts – ΣSθreactants
ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s) = (40.0) + (214.0) – (92.9) = +161.0 J mol–1 K–1
ΔSθsurr is –ΔHθ/T = –(179000/T)
ΔSθtot = ΔSθsys + ΔSθsurr
ΔSθtot = (+161) + (–179000/T) = 161 – 179000/T
If we then substitute various values of T (in Kelvin) you can calculate when the reaction becomes feasible.
For T = 298K (room temperature)
ΔSθtot = 161 – 179000/298 = –439.7 J mol–1 K–1, no good, negative entropy change
For T = 500K (fairly high temperature for an industrial process)
ΔSθtot = 161 – 179000/500 = –197.0, still no good
For T = 1200K (limekiln temperature)
ΔSθtot = 161 – 179000/1200 = +11.8 J mol–1 K–1, definitely feasible, overall positive entropy change
Now assuming ΔSθsys is approximately constant with temperature change and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall. But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800–900oC ΔSθtot becomes plus overall, so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.
You can approach the problem in another more efficient way by solving the total entropy expression for T at the point when the total entropy change is zero. At this point calcium carbonate, calcium oxide and carbon dioxide are at equilibrium.
ΔSθtot–equilib = 0 = 161 – 179000/T, 179000/T = 161, T = 179000/161 = 1112 K
This means that 1112 K is the minimum temperature to get an economic yield. Well at first sight anyway. In fact because the carbon dioxide is swept away in the flue gases so an equilibrium is never truly attained so limestone continues to decompose even at lower temperatures.
It takes 0.26 minutes to travel 1000 feet
<u>Solution:</u>
Given that car traveling at a constant speed travels 175 miles in four hours
Distance = 175 miles
Time taken = 4 hours
Convert the units to feet and minute
Given that,
1 mile = 5280 feet
175 miles = 5280 x 175 feet = 918720 feet
Also we know that,
1 hour = 60 minutes
4 hours = 60 x 4 minutes = 240 minutes
Thus, we got,
Distance = 918720 feet
Time taken = 240 minutes
<em><u>Find the speed of car</u></em>
<em><u>Speed is given by formula:</u></em>


Thus speed of car is 3828 feet per minute
<em><u>How many minutes will it take for the car to travel 1000 feet?</u></em>
Let "x" be the minutes needed for 1000 feet
speed of car is 3828 feet per minute
1 minute = 3828 feet
x minute = 1000 feet
This forms a proportion. We can solve by cross multiplying

Thus it takes 0.26 minutes to travel 1000 feet