HNO3 and H2SO4 are Arrhenius acids which will increase the concentration of H+ when dissolved in water.
KOH and Ca(OH)2 are Arrhenius bases that increase the concentration of OH- when dissociated in water.
Answer:
The equilibrium expression is:
CoC2O4(s)⇌Co2+(aq)+C2O2−4(aq)
For this reaction:
Ksp = [Co2+][C2O2−4]=1.96×10−8
Explanation:
Batteries will not clot if cobalt ions are removed from its cells. Some blood collection tubes contain salts of the oxalate ion,
C2O2−4
, for this purpose. At sufficiently high concentrations, the calcium
and oxalate ions form solid, CoC2O4·H2O (which also contains water bound in the solid). The concentration of Co2+ in a sample of blood serum is 2.2 × 10–3M. What concentration of
C2O2−4
ion must be established before CoC2O4·H2O begins to precipitate.
CoC2O4 does not appear in this expression because it is a solid. Water does not appear because it is the solvent.
Solid CoC2O4 does not begin to form until Q equals Ksp. Because we know Ksp and [Co2+], we can solve for the concentration of
C2O2−4
that is necessary to produce the first trace of solid:
A0 = 1
a1 = 2
a2 = 1
a3 = 2
This can be solved by guessing and checking and making sure that all atoms on the left side are accounted for on the right side. Both sides must have the same amount of atoms or the balancing is not correct.
A coordination complex consists of a central atom or Jon, which usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligand or complexing agents