<span>In the 19th century, scientists realized that gases in the atmosphere cause a "greenhouse effect" which affects the planet's temperature. These scientists were interested chiefly in the possibility that a lower level of carbon dioxide gas might explain the ice ages of the distant past. At the turn of the century, Svante Arrhenius calculated that emissions from human industry might someday bring a global warming. Other scientists dismissed his idea as faulty. In 1938, G.S. Callendar argued that the level of carbon dioxide was climbing and raising global temperature, but most scientists found his arguments implausible. It was almost by chance that a few researchers in the 1950s discovered that global warming truly was possible. In the early 1960s, C.D. Keeling measured the level of carbon dioxide in the atmosphere: it was rising fast. Researchers began to take an interest, struggling to understand how the level of carbon dioxide had changed in the past, and how the level was influenced by chemical and biological forces. They found that the gas plays a crucial role in climate change, so that the rising level could gravely affect our future. (This essay covers only developments relating directly to carbon dioxide, with a separate essay for Other Greenhouse Gases. Theories are discussed in the essay on Simple Models of Climate.)</span>
This equation represents a single replacement reaction. Single replacement reactions consist of one element reacting with one compound on the reactant side (left side of the equation) and they form one new element and one new compound on the product side of the equation (right side).
<u>Answer:</u> The expression for equilibrium constant is ![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)
<u>Explanation:</u>
Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as 
For the general chemical equation:

The expression for
is given as:
![K_c=\frac{[C]^c[D]^d}{[A]^a[B]^b}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BC%5D%5Ec%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%5BB%5D%5Eb%7D)
For the given chemical reaction:

The expression for
is given as:
![K_{eq}=\frac{[HOCl]^2[HgO.HgCl_2]}{[HgO]^2[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%5BHgO.HgCl_2%5D%7D%7B%5BHgO%5D%5E2%5BH_2O%5D%5BCl_2%5D%5E2%7D)
The concentration of solid is taken to be 0.
So, the expression for
is given as:
![K_{eq}=\frac{[HOCl]^2}{[H_2O][Cl_2]^2}](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cfrac%7B%5BHOCl%5D%5E2%7D%7B%5BH_2O%5D%5BCl_2%5D%5E2%7D)
Answer:
Check the explanation
Explanation:
When,
pH = -log[H+] = 3.30
[H+] = 

![alpha[Y^-4] = [H+]^6 + Ka1[H+]^5 + Ka1Ka2[H+]^4 + Ka1Ka2Ka3[H+]^3 + Ka1Ka2Ka3Ka4[H+]^2 + Ka1Ka2Ka3Ka4Ka5[H+] + Ka1Ka2Ka3Ka4Ka5Ka6](https://tex.z-dn.net/?f=alpha%5BY%5E-4%5D%20%3D%20%5BH%2B%5D%5E6%20%2B%20Ka1%5BH%2B%5D%5E5%20%2B%20Ka1Ka2%5BH%2B%5D%5E4%20%2B%20Ka1Ka2Ka3%5BH%2B%5D%5E3%20%2B%20Ka1Ka2Ka3Ka4%5BH%2B%5D%5E2%20%2B%20Ka1Ka2Ka3Ka4Ka5%5BH%2B%5D%20%2B%20Ka1Ka2Ka3Ka4Ka5Ka6)
= 
= 
When,
pH = -log[H+] = 10.15
[H+] = 
Ka1 = 1 ; Ka2 = 0.0316 ; Ka3 = 0.01 ; Ka4 = 0.002 ; Ka5 =
; Ka6 = 
= 
= 