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valina [46]
3 years ago
9

Given the following information: Mass of proton = 1.00728 amu Mass of neutron = 1.00866 amu Mass of electron = 5.486 × 10^-4 amu

Speed of light = 2.9979 × 10^8 m/s Calculate the nuclear binding energy (absolute value) of 3Li^6. which has an atomic mass of 6.015126 amu. J/mol.
Chemistry
1 answer:
lesya692 [45]3 years ago
3 0

<u>Answer:</u> The nuclear binding energy of the given element is 2.938\times 10^{12}J/mol

<u>Explanation:</u>

For the given element _3^6\textrm{Li}

Number of protons = 3

Number of neutrons = (6 - 3) = 3

We are given:

m_p=1.00728amu\\m_n=1.00866amu\\A=6.015126amu

M = mass of nucleus = (n_p\times m_p)+(n_n\times m_n)

M=[(3\times 1.00728)+(3\times 1.00866)]=6.04782amu

Calculating mass defect of the nucleus:

\Delta m=M-A\\\Delta m=[6.04782-6.015126)]=0.032694amu=0.032694g/mol

Converting this quantity into kg/mol, we use the conversion factor:

1 kg = 1000 g

So,  0.032694g/mol=0.032694\times 10^{-3}kg/mol

To calculate the nuclear binding energy, we use Einstein equation, which is:

E=\Delta mc^2

where,

E = Nuclear binding energy = ? J/mol

\Delta m = Mass defect = 0.032694\times 10^{-3}kg/mol

c = Speed of light = 2.9979\times 10^8m/s

Putting values in above equation, we get:

E=0.032694\times 10^{-3}kg/mol\times (2.9979\times 10^8m/s)^2\\\\E=2.938\times 10^{12}J/mol

Hence, the nuclear binding energy of the given element is 2.938\times 10^{12}J/mol

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Q.No. 1:

            You have 20.0 g of CaCO₃. You decompose it by heat, and weigh the calcium oxide that  remains. You have 10.3 grams. What is the % yield?

Answer:

               %age Yield = 92.37 %

Solution:

               The balance chemical equation for given decomposition reaction is;

                                           CaCO₃ → CaO + CO₂

Step 1: <u>Calculate Moles of CaCO₃:</u>

                Moles  =  Mass / M.Mass

                Moles  =  20.0 g / 100.08 g/mol

                Moles  =  0.199 moles of CaCO₃

Step 2: <u>Calculate theoretical amount of CaO produced;</u>

According to equation,

              1 moles of CaCO₃ produced  =  1 mole of CaO

So,

           0.199 moles of CaCO₃ will produce  =  X moles of CaO

Solving for X,

                     X  =  0.199 mol × 1 mol / 1 mol

                     X  =  0.199 mol of CaO

Also,

         Mass  =  Moles × M.Mass

         Mass  =  0.199 mol × 56.07 g/mol

         Mass  =  11.15 g of CaO

Step 3: <u>Calculate %age Yield as;</u>

         %age Yield  =  Actual Yield / Theoretical Yield × 100

         %age Yield  =  10.3 g / 11.15 g × 100

         %age Yield = 92.37 %

___________________________________________

Q.No. 2:

            A student makes sodium chloride by buming 2.3 grams of sodium in chlorine  gas. If the yield is 90%, how much sodium chloride is made?

Answer:

               Actual Yield =  5.785 g of NaCl

Solution:

               The balance chemical equation for given decomposition reaction is;

                                           2 Na + Cl₂ → 2 NaCl

Step 1: <u>Calculate Moles of Na:</u>

                Moles  =  Mass / M.Mass

                Moles  =  2.3 g / 23 g/mol

                Moles  =  0.10 moles of Na

Step 2: <u>Calculate theoretical amount of NaCl produced;</u>

According to equation,

              2 moles of Na produced  =  2 moles of NaCl

So,

           0.10 moles of Na will produce  =  X moles of NaCl

Solving for X,

                     X  =  0.10 mol × 2 mol / 2 mol

                     X  =  0.10 mol of NaCl

Also,

         Mass  =  Moles × M.Mass

         Mass  =  0.10 mol × 58.44 g/mol

         Mass  =  5.844 g of NaCl

Step 3: <u>Calculate Actual Yield as;</u>

         %age Yield  =  Actual Yield / Theoretical Yield × 100

Or,

         Actual Yield  =  %age Yield × Theoretical Yield ÷ 100

         Actual Yield  =  99 × 5.844 g ÷ 100

         Actual Yield =  5.785 g of NaCl

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Q.No. 3:

            For the chemical reaction Mg(s) + 2 HCl (aq) → H₂ (g) + MgCl₂ (aq) calculate the  % yield if 100 grams of magnesium react with excess HCl to produce 310 grams of MgCl₂.

Answer:

               %age Yield = 79.13 %

Solution:

               The balance chemical equation for given decomposition reaction is;

                                           Mg + 2 HCl → MgCl₂ + H₂

Step 1: <u>Calculate Moles of Mg:</u>

                Moles  =  Mass / M.Mass

                Moles  =  100 g / 24.30 g/mol

                Moles  =  4.11 moles of Mg

Step 2: <u>Calculate theoretical amount of MgCl₂ produced;</u>

According to equation,

              1 mole of Mg produced  =  1 mole of MgCl₂

So,

           4.11 moles of Mg will produce  =  X moles of MgCl₂

Solving for X,

                     X  =  4.11 mol × 1 mol / 1 mol

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Also,

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         %age Yield  =  Actual Yield / Theoretical Yield × 100

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