A chemist adds 0.50L of a 0.485 M copper(II) sulfate CuSO4 solution to a reaction flask. Calculate the millimoles of copper(II)
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Answer:
1. When observing a positive test for the jones reagent and negative for the Lucas test, it indicates that it is in the presence of a primary alcohol.
Jones reagent behaves like a strong oxidant, where it transforms the primary alcohols into carboxylic acids and the secondary alcohols into ketones. Tertiary alcohols do not react.
With the Lucas test, tertiary alcohols react immediately producing turbidity, while secondary alcohols do so in five minutes. Primary alcohols do not react significantly with Lucas reagent at room temperature.
2. No reaction (See the attached drawing)
3. (see the attached drawing)
Answer:
Explanation:
Henry's law states that the solubility of a gas is directly proportional to its partial pressure. The equation may be written as:
Where is Henry's law constant.
Our strategy will be to identify the Henry's law constant for oxygen given the initial conditions and then use it to find the solubility at different conditions.
Given initially:
Also, at sea level, we have an atmospheric pressure of:
Given mole fraction:
According to Dalton's law of partial pressures, the partial pressure of oxygen is equal to the product of its mole fraction and the total pressure:
Then the equation becomes:
Solve for :
Now we're given that at an altitude of 12,000 ft, the atmospheric pressure is now:
Apply Henry's law using the constant we found: