Following reaction is involved in above system
HOCl(aq) ↔ H+(aq) + OCl-<span>(aq)
</span>OCl-(aq) + H2O(l) ↔ HOCl(aq) + OH-<span>(aq)
</span>
Now, if the system is obeys 1st order kinetics we have
K = [OCl-][H+<span>]/[HOCl] ............. (1)
</span>∴ [HOCl-] / [OCl-] = [H+] (1 / 3.0 * 10-8<span>) ............. (2)
</span>
and now considering that system is obeying 2nd order kinetics, we have
K = [OH-][HOCl-] / [OCl-] ................. (3<span>)
</span>Subs 2 in 3 we get
K = [OH-][H+] (1 / 3.0 * 10-8<span>)
</span>we know that, [OH-][H+] = 10<span>-14
</span>∴K = 3.3 * 10<span>-7
</span>
Thus, correct answer is e i.e none of these
Physical Change
It is being changed by the sun
Answer:
Copper ions are reduced into copper atoms.
Cu²⁺₍aq₎ + 2e⁻ → Cu₍s₎
Explanation:
During electrolysis, the positive H⁺ and Cu⁺ ions move to the negative cathode and negative OH⁻ and Cl⁻ ions move to the positive anode.
At cathode, copper ions are preferentially discharged due to the low electromotive force required to discharge them compared to the hydrogen ion. The copper ions gain the two electrons lost by the chloride ions when the are discharged. (2 Cl⁻₍aq₎ → Cl₂₍g₎ + 2e⁻)
Thus the half equation is as follows:
Cu²⁺₍aq₎ + 2e⁻ → Cu₍s₎
they will both do the exact same thing, as long as they are bothh identical
Answer:
it is possible to remove 99.99% Cu2 by converting it to Cu(s)
Explanation:
So, from the question/problem above we are given the following ionic or REDOX equations of reactions;
Cu2+ + 2e- <--------------------------------------------------------------> Cu (s) Eo= 0.339 V
Sn2+ + 2e- <---------------------------------------------------------------> Sn (s) Eo= -0.141 V
In order to convert 99.99% Cu2 into Cu(s), the equation of reaction given below is needed:
Cu²⁺ + Sn ----------------------------------------------------------------------------> Cu + Sn²⁺.
Therefore, E°[overall] = 0.339 - [-0.141] = 0.48 V.
Therefore, the change in Gibbs' free energy, ΔG° = - nFE°. Where E° = O.48V, n= 2 and F = 96500 C.
Thus, ΔG° = - 92640.
This is less than zero[0]. Therefore, it is possible to remove 99.99% Cu2 by converting it to Cu(s) because the reaction is a spontaneous reaction.
