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Gelneren [198K]
3 years ago
12

Assume that the complete combustion of one mole of glucose, a monosaccharide, to carbon dioxide and water liberates 2870 kJ2870

kJ of energy (ΔG°′=−2870 kJ/mol(ΔG°′=−2870 kJ/mol ). If the energy generated by the combustion of glucose is entirely converted to the synthesis of a hypothetical compound X, calculate the number of moles of the compound that could theoretically be generated. Use the value ΔG°′compound X=−54.1 kJ/molΔG°′compound X=−54.1 kJ/mol . Round your answer to two significant figures.
Chemistry
1 answer:
Lubov Fominskaja [6]3 years ago
7 0

Answer:

number of moles of the compound \approx 53 mole

Explanation:

Given that:

The total energy liberated = - 2870 kJ  ( here , the negative sign typical implies the release of energy due to the combustion reaction)

The equation of the reaction can be represented as:

\mathbf{C_6H_{12}O_6_{(s)} + 6O_{2(g)} \to 6CO_{2(g)}+6H_2O_{(l)}}

The energy needed to synthesize 1 mole of compound X  = - 54.1 kJ.mol

Thus;

The total energy = numbers of moles of compound × Energy needed to synthesize  1 mole of compound X

Making the numbers of moles of the compound the subject; we have;

numbers of moles of compound = numbers  \ of \  moles  \ of \  compound =  \dfrac{total \ energy }{Energy \  needed  \ to  \ synthesize \   1  \ mole \  of \  compound  \ X}numbers  \ of \  moles  \ of \  compound =  \dfrac{-2870  \ kJ }{-54.1  \ kJ/mol}

number of moles of the compound = 53.04990  mole

number of moles of the compound \approx 53 mole to two significant figure

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How many formula units make up 24.2 g of magnesium chloride (MgCl2)?<br><br> Help!!
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Answer:

Approximately 1.53 \times 10^{23} formula units (0.254\; \rm mol).

Explanation:

Refer to a modern periodic table for the relative atomic mass of magnesium (\rm Mg) and chlorine (\rm Cl):

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In other words, the mass of 1\; \rm mol of \rm Mg atoms would be (approximately) 24.305\; \rm g.

Likewise, the mass of 1\; \rm mol of \rm Cl atoms would be approximately 35.45\; \rm g.

One formula unit of the ionic compound \rm MgCl_{2} includes exactly as many atoms as there are in the given formula. The formula mass of a compound is the mass of 1\; \rm mol of the formula units of this compound.

The formula \rm MgCl_{2} includes one \rm Mg atom and two \rm Cl atoms.

Hence, every formula unit of \rm MgCl_{2} \! would include the same number of atoms: one \rm Mg\! atom and two \rm Cl\! atoms. There would be 1\; \rm mol of \rm Mg atoms and 2\; \rm mol of \rm Cl atoms in 1\; \rm mol\! of \rm MgCl_{2} formula units.

Thus, the mass of 1\; \rm mol\! of \rm MgCl_{2} formula units would be equal to the mass of 1\; \rm mol of \rm Mg atoms plus the mass of 2\; \rm mol of \rm Cl atoms. (The mass of 1\; \rm mol\!\! of each atom could be found from the relative atomic mass of each element.)

\begin{aligned}& M({\rm MgCl_{2}}) \\ =\; & 24.305\; {\rm g \cdot mol^{-1}} + 2\times {\rm 35.45 \; \rm g \cdot mol^{-1}} \\ =\; & 95.205\; \rm g \cdot mol^{-1}\end{aligned}.

In other words, the formula mass of \rm MgCl_{2} is 95.205\; \rm g \cdot mol^{-1}.

Therefore, the number of formula units in m = 24.2\; \rm g of \rm MgCl_{2} would be:

\begin{aligned}n &= \frac{m({\rm MgCl_{2}})}{M({\rm MgCl_{2}})} \\ &= \frac{24.2\; \rm g}{95.205\; \rm g\cdot mol^{-1}} \\ & \approx 0.254\; \rm mol\end{aligned}.

Multiple n by Avogadro's Number N_{A} \approx 6.022 \times 10^{23}\; \rm mol^{-1} to estimate the number of formula units in 0.254\; \rm mol:

\begin{aligned}N &= n \cdot N_{A} \\ &\approx 0.254\; \rm mol \times 6.022 \times 10^{23}\; \rm mol^{-1} \\ &\approx 1.53\times 10^{23}\end{aligned}.

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