Answer:
Physical Properties
Explanation:
You are able to see physical properties but are unable to see chemical properties.
True. For example, electron domain geometry and molecular geometry of water and ammonia are different.
An aqueous solution in a 55 gallon (208 l drum), characterized by minimal buffering capacity, received 4kg of phenol and 1.5 kg of sodium phenate. What is the ph of the solution. The pka of phenol = 9.98. Mw of phenol and sodium phenate are 94 g/mol and 116 g/mol, respectively.
Volume of solution = 55 gallons = 208.2 L [ 1 gallon = 3.78 L]
moles of phenol = mass / molar mass = 4000 g / 94 = 42.55 moles
moles of sodium phenate = mass / molar mass = 1500 / 116 = 12.93 moles
pKa of phenol = 9.98
We know that the pH of buffer is calculated using Hendersen Hassalbalch's equation
pH = pKa + log [salt] / [acid]
volume is same for both the sodium phenate and phenol has we can directly take the moles of each in the formula
pH = 9.98 + log [12.93 / 42.55] = 9.46
Answer:
2. 181.25 K.
3. 0.04 atm.
Explanation:
2. Determination of the temperature.
Number of mole (n) = 2.1 moles
Pressure (P) = 1.25 atm
Volume (V) = 25 L
Gas constant (R) = 0.0821 atm.L/Kmol
Temperature (T) =?
The temperature can be obtained by using the ideal gas equation as illustrated below:
PV = nRT
1.25 × 25 = 2.1 × 0.0821 × T
31.25 = 0.17241 × T
Divide both side by 0.17241
T = 31.25 / 0.17241
T = 181.25 K
Thus, the temperature is 181.25 K.
3. Determination of the pressure.
Number of mole (n) = 10 moles
Volume (V) = 5000 L
Temperature (T) = –10 °C = –10 °C + 273 = 263 K
Gas constant (R) = 0.0821 atm.L/Kmol
Pressure (P) =?
The pressure can be obtained by using the ideal gas equation as illustrated below:
PV = nRT
P × 5000 = 10 × 0.0821 × 263
P × 5000 = 215.923
Divide both side by 5000
P = 215.923 / 5000
P = 0.04 atm
Thus, the pressure is 0.04 atm
