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slega [8]
3 years ago
11

Find ΔHrxn for the following reaction: 2PbS(s)+3O2(g)→2PbO(s)+2SO2(g)

Chemistry
1 answer:
ch4aika [34]3 years ago
5 0

Answer:

ΔH°rxn = -827.5 kJ

Explanation:

Let's consider the following balanced equation.

2 PbS(s) + 3 O₂(g) → 2 PbO(s) + 2 SO₂(g)

We can calculate the standard enthalpy of reaction (ΔH°rxn) from the standard enthalpies of formation (ΔH°f) using the following expression.

ΔH°rxn = [2 mol × ΔH°f(PbO(s)) + 2 mol × ΔH°f(SO₂(g) )] - [2 mol × ΔH°f(PbS(s)) + 3 mol × ΔH°f(O₂(g) )]

ΔH°rxn = [2 mol × ΔH°f(PbO(s)) + 2 mol × ΔH°f(SO₂(g) )] - [2 mol × ΔH°f(PbS(s)) + 3 mol × ΔH°f(O₂(g) )]

ΔH°rxn = [2 mol × (-217.32 kJ/mol) + 2 mol × (-296.83)] - [2 mol × (-100.4) + 3 mol × 0 kJ/mol]

ΔH°rxn = -827.5 kJ

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An analytical chemist is titrating of a solution of propionic acid with a solution of 224.9 ml of a 0.6100M solution of propioni
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<u>Answer:</u> The pH of acid solution is 4.58

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}    .....(1)

  • <u>For KOH:</u>

Molarity of KOH solution = 1.1000 M

Volume of solution = 41.04 mL

Putting values in equation 1, we get:

1.1000M=\frac{\text{Moles of KOH}\times 1000}{41.04}\\\\\text{Moles of KOH}=\frac{1.1000\times 41.04}{1000}=0.04514mol

  • <u>For propanoic acid:</u>

Molarity of propanoic acid solution = 0.6100 M

Volume of solution = 224.9 mL

Putting values in equation 1, we get:

0.6100M=\frac{\text{Moles of propanoic acid}\times 1000}{224.9}\\\\\text{Moles of propanoic acid}=\frac{0.6100\times 224.9}{1000}=0.1372mol

The chemical reaction for propanoic acid and KOH follows the equation:

                 C_2H_5COOH+KOH\rightarrow C_2H_5COOK+H_2O

<u>Initial:</u>          0.1372         0.04514  

<u>Final:</u>           0.09206          -                0.04514

Total volume of solution = [224.9 + 41.04] mL = 265.94 mL = 0.26594 L     (Conversion factor:  1 L = 1000 mL)

To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:

pH=pK_a+\log(\frac{[\text{salt}]}{[acid]})

pH=pK_a+\log(\frac{[C_2H_5COOK]}{[C_2H_5COOH]})

We are given:  

pK_a = negative logarithm of acid dissociation constant of propanoic acid = 4.89

[C_2H_5COOK]=\frac{0.04514}{0.26594}

[C_2H_5COOH]=\frac{0.09206}{0.26594}

pH = ?  

Putting values in above equation, we get:

pH=4.89+\log(\frac{(0.04514/0.26594)}{(0.09206/0.26594)})\\\\pH=4.58

Hence, the pH of acid solution is 4.58

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