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mrs_skeptik [129]
2 years ago
7

Which of the following is NOT an exothermic reaction?

Chemistry
1 answer:
nignag [31]2 years ago
7 0

Answer:

a) dissolving sugar in water to form a mixture of sugar and water

Explanation:

exothermic reaction is reaction in which is heat is released during the reaction and endothermic reaction is a reaction in which heat is needed or required for the reaction to take place

all the options excluding option A) is exothermic as during the process of formation of bonds in oxidation, heat is released. rusting too is a slow form of oxidation and thus an exothermic reaction.

dissolving sugar in water is not exothermic reaction because their is no heat released. the sugar molecules simply disperses in the water molecules and form a solution.

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A 8.2 L sample of gas has a pressure of 0.8 atm at a temperature of 259 K. If the temperature increases to 301 K, causing the vo
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what volume of co2 is produced at stp when 270g of glucose are consumed in the following reaction? c6h12o6 + 6o2(g) -> 6co2 (
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Answer:

202 L

Explanation:

Step 1: Write the balanced equation

C₆H₁₂O₆ + 6 O₂(g) ⇒ 6 CO₂(g) + 6 H₂O(l)

Step 2: Calculate the moles corresponding to 270 g of C₆H₁₂O₆

The molar mass of C₆H₁₂O₆ is 180.16 g/mol.

270 g × 1 mol/180.16 g = 1.50 mol

Step 3: Calculate the moles of CO₂ generated from 1.50 moles of glucose

The molar ratio of C₆H₁₂O₆ to CO₂ is 1:6. The moles of CO₂ formed are 6/1 × 1.50 mol = 9.00 mol

Step 4: Calculate the volume of 9.00 moles of CO₂ at STP

The volume of 1 mole of an ideal gas at STP is 22.4 L.

9.00 mol × 22.4 L/mol = 202 L

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What is the name of this unstable isotope from number 9?
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The following data were collected for the rate of disappearance of NO in the reaction 2NO(g)+O2(g)→2NO2(g)::
Anit [1.1K]

Answer:

a) The rate law is: v = k[NO]² [O₂]

b) The units are: M⁻² s⁻¹

c) The average value of the constant is: 7.11 x 10³ M⁻² s⁻¹

d) The rate of disappearance of NO is 0.8 M/s

e) The rate of disappearance of O₂ is 0.4 M/s

Explanation:

The experimental rates obtained can be expressed as follows:

v1 = k ([NO]₁)ᵃ ([O₂]₁)ᵇ = 1.41 x 10⁻² M/s

v2 = k ([NO]₂)ᵃ ([O₂]₂)ᵇ = 5.64 x 10⁻² M/s

v3 = k ([NO]₃)ᵃ ([O₂]₃)ᵇ = 1.13 x 10⁻¹ M/s

where:

k = rate constant

[NO]₁ = concentration of NO in experiment 1

[NO]₂ = concentration of NO in experiment 2

[NO]₃ = concentration of NO in experiment 3

[O₂]₁ = concentration of O₂ in experiment 1

[O₂]₂ = concentration of O₂ in experiment 2

[O₂]₃ = concentration of O₂ in experiment 3

a and b = order of the reaction for each reactive respectively.

We can see these equivalences:

[NO]₂ = 2[NO]₁

[O₂]₂ = [O₂]₁

[NO]₃ = [NO]₂

[O₂]₃ = 2[O₂]₂

So, v2 can be written in terms of the concentrations used in experiment 1 replacing [NO]₂ for 2[NO]₁ and [O₂]₂ by [O₂]₁ :

v2 = k (2 [NO]₁)ᵃ ([O₂]₁)ᵇ

If we rationalize v2/v1, we will have:

v2/v1 = k *2ᵃ * ([NO]₁)ᵃ * ([O₂]₁)ᵇ / k * ([NO]₁)ᵃ * ([O₂]₁)ᵇ (the exponent "a" has been distributed)

v2/v1 = 2ᵃ

ln(v2/v1) = a ln2

ln(v2/v1) / ln 2 = a

a = 2

(Please review the logarithmic properties if neccesary)

In the same way, we can find b using the data from experiment 2 and 3 and writting v3 in terms of the concentrations used in experiment 2:

v3/v2 = k ([NO]₂)² * 2ᵇ * ([O₂]₁)ᵇ / k * ([NO]₂)² * ([O₂]₂)ᵇ

v3/v2 = 2ᵇ

ln(v3/v2) = b ln 2

ln(v3/v2) / ln 2 = b

b = 1

Then, the rate law for the reaction is:

<u>v = k[NO]² [O₂]</u>

Since the unit of v is M/s and the product of the concentrations will give a unit of M³, the units of k are:

M/s = k * M³

M/s * M⁻³ = k

<u>M⁻² s⁻¹ = k </u>

To obtain the value of k, we can solve this equation for every experiment:

k = v / [NO]² [O₂]

for experiment 1:

k = 1.41 x 10⁻² M/s / (0.0126 M)² * 0.0125 M = 7.11 x 10³ M⁻² s⁻¹

for experiment 2:

k = 7.11 x 10³ M⁻² s⁻¹

for experiment 3:

k = 7.12 x 10³ M⁻² s⁻¹

The average value of k is then:

(7.11 + 7.11 + 7.12) x 10³ M⁻² s⁻¹ / 3 = <u>7.11 x 10³ M⁻² s⁻¹ </u>

The rate of the reaction when [NO] = 0.0750 M and [O2] =0.0100 M is:

v = k [NO]² [O₂]

The rate of the reaction in terms of the disappearance of NO can be written this way:

v = 1/2(Δ [NO] / Δt) (it is divided by 2 because of the stoichiometric coefficient of NO)

where (Δ [NO] / Δt) is the rate of disappearance of NO.

Then, calculating v with the data provided by the problem:

v = 7.11 x 10³ M⁻² s⁻¹ * (0.0750M)² * 0.0100M = 0.4 M/s

Then, the rate of disappearance of NO will be:

2v = Δ [NO] / Δt = <u>0.8 M/s</u>

The rate of disappearance of O₂ has to be half the rate of disappearance of NO because two moles of NO react with one of O₂. Then Δ [O₂] / Δt = <u>0.4 M/s</u>

With calculations:

v = Δ [O₂] / Δt = 0.4 M/s (since the stoichiometric coefficient is 1, the rate of disappearance of O₂ equals the rate of the reaction).

3 0
3 years ago
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