Answer:
The advantages of using an indicator to inform pH measurements:
It gives a mathematically result of the pH, in addition, it gives the precise pH of solvent, and it also gives an idea of the straight of the solution also.
Now, the advantage of using a pH meter:
It is a rapid method to characterize between acids, bases. However, this method does not show how strong acid or base actually are, plus it tends to gives a range of acidity or basicity not quite accurate as a result.
Answer is 0.289nm.
Explanation: The wt % of Fe and wt % of V is given for a Fe-V alloy.
wt % of Fe in Fe-V alloy = 85%
wt % of V in Fe-V alloy = 15%
We need to calculate edge length of the unit cell having bcc structure.
Using density formula,

For calculating edge length,

For calculating
, we use the formula

Similarly for calculating
, we use the formula

From the periodic table, masses of the two elements can be written


Specific density of both the elements are

Putting
and
formula's in edge length formula, we get
![a=\left [\frac{Z\left (\frac{100}{\frac{(wt\%)_{Fe}}{M_{Fe}}+\frac{(wt\%)_{Fe}}{M_{Fe}}} \right )}{N_A\left (\frac{100}{\frac{(wt\%)_V}{\rho_V}+\frac{(wt\%)_V}{\rho_V}} \right )} \right ]^{1/3}](https://tex.z-dn.net/?f=a%3D%5Cleft%20%5B%5Cfrac%7BZ%5Cleft%20%28%5Cfrac%7B100%7D%7B%5Cfrac%7B%28wt%5C%25%29_%7BFe%7D%7D%7BM_%7BFe%7D%7D%2B%5Cfrac%7B%28wt%5C%25%29_%7BFe%7D%7D%7BM_%7BFe%7D%7D%7D%20%20%5Cright%20%29%7D%7BN_A%5Cleft%20%28%5Cfrac%7B100%7D%7B%5Cfrac%7B%28wt%5C%25%29_V%7D%7B%5Crho_V%7D%2B%5Cfrac%7B%28wt%5C%25%29_V%7D%7B%5Crho_V%7D%7D%20%20%5Cright%20%29%7D%20%20%5Cright%20%5D%5E%7B1%2F3%7D)
![a=\left [\frac{2atoms/\text{unit cell}\left (\frac{100}{\frac{85\%}{55.85g/mol}+\frac{15\%}{50.941g/mol}} \right )}{(6.023\times10^{23}atoms/mol)\left (\frac{100}{\frac{85\%}{7.874g/cm^3}+\frac{15\%}{6.10g/cm^3}} \right )} \right ]^{1/3}](https://tex.z-dn.net/?f=a%3D%5Cleft%20%5B%5Cfrac%7B2atoms%2F%5Ctext%7Bunit%20cell%7D%5Cleft%20%28%5Cfrac%7B100%7D%7B%5Cfrac%7B85%5C%25%7D%7B55.85g%2Fmol%7D%2B%5Cfrac%7B15%5C%25%7D%7B50.941g%2Fmol%7D%7D%20%20%5Cright%20%29%7D%7B%286.023%5Ctimes10%5E%7B23%7Datoms%2Fmol%29%5Cleft%20%28%5Cfrac%7B100%7D%7B%5Cfrac%7B85%5C%25%7D%7B7.874g%2Fcm%5E3%7D%2B%5Cfrac%7B15%5C%25%7D%7B6.10g%2Fcm%5E3%7D%7D%20%20%5Cright%20%29%7D%20%20%5Cright%20%5D%5E%7B1%2F3%7D)
By calculating, we get

The mass decay rate is of the form

where
m₀ = 3000 g,the initial mass
k = the decay constant
t = time, years.
Because the half-life is 30 years, therefore

After 60 years, the mass remaining is

Answer: 750 g