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3 years ago

The diagram below shows four possible collisions between ethene and hydrogen chloride molecules.

Chemistry

1 answer:

mariarad [96]3 years ago

8 0

One of the factors that the collision theory encompass to explain the rate of reactions is the orientation of the collisions.

In some reactions the only some special orientations yield effective collisions (those which will result in a chemical change).

In the case of the ehtylene and hydrogen chloride, the hydrogen end of the hydrogen chloride molecule must collide with the double bond of the ehtene molecule, to transform the change the c-c double bond iinto a single bond.

This approach is represented by the collision 1 of the diagram.

For your information, when the Chloride end of the hygrogen chloride molecule approachs the double bond of the ethylene molecule, the excces of negative charge on the chloride (due to its electronegativity) will be repeled by the electron density on the double bond, and the molecules will bounce instead of react.

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(1) The number of grams needed of each fuel $(C_2H_6)\text{ and }(C_4H_{10})$ are 19.23 g and 20.41 g respectively.

(2) The number of moles of each fuel $(C_2H_6)\text{ and }(C_4H_{10})$ are 0.641 moles and 0.352 moles respectively.

(3) The balanced chemical equation for the combustion of the fuels.

$C_2H_6+\frac{7}{2}O_2\rightarrow 2CO_2+3H_2O$

$C_4H_{10}+\frac{13}{2}O_2\rightarrow 4CO_2+5H_2O$

(4) The number of moles of $CO_2$ produced by burning each fuel is 1.28 mole and 1.41 mole respectively.

The fuel that emitting least amount of $CO_2$ is $C_2H_6$

Explanation :

Part 1 :

First we have to calculate the number of grams needed of each fuel $(C_2H_6)\text{ and }(C_4H_{10})$ .

As, 52 kJ energy required amount of $C_2H_6$ = 1 g

So, 1000 kJ energy required amount of $C_2H_6$ = $\frac{1000}{52}=19.23g$

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As, 49 kJ energy required amount of $C_4H_{10}$ = 1 g

So, 1000 kJ energy required amount of $C_4H_{10}$ = $\frac{1000}{49}=20.41g$

Part 2 :

Now we have to calculate the number of moles of each fuel $(C_2H_6)\text{ and }(C_4H_{10})$ .

Molar mass of $C_2H_6$ = 30 g/mole

Molar mass of $C_4H_{10}$ = 58 g/mole

$\text{ Moles of }C_2H_6=\frac{\text{ Mass of }C_2H_6}{\text{ Molar mass of }C_2H_6}=\frac{19.23g}{30g/mole}=0.641moles$

and,

$\text{ Moles of }C_4H_{10}=\frac{\text{ Mass of }C_4H_{10}}{\text{ Molar mass of }C_4H_{10}}=\frac{20.41g}{58g/mole}=0.352moles$

Part 3 :

Now we have to write down the balanced chemical equation for the combustion of the fuels.

The balanced chemical reaction for combustion of $C_2H_6$ is:

$C_2H_6+\frac{7}{2}O_2\rightarrow 2CO_2+3H_2O$

and,

The balanced chemical reaction for combustion of $C_4H_{10}$ is:

$C_4H_{10}+\frac{13}{2}O_2\rightarrow 4CO_2+5H_2O$

Part 4 :

Now we have to calculate the number of moles of $CO_2$ produced by burning each fuel to produce 1000 kJ.

$C_2H_6+\frac{7}{2}O_2\rightarrow 2CO_2+3H_2O$

From this we conclude that,

As, 1 mole of $C_2H_6$ react to produce 2 moles of $CO_2$

As, 0.641 mole of $C_2H_6$ react to produce $0.641\times 2=1.28$ moles of $CO_2$

and,

$C_4H_{10}+\frac{13}{2}O_2\rightarrow 4CO_2+5H_2O$

From this we conclude that,

As, 1 mole of $C_4H_{10}$ react to produce 4 moles of $CO_2$

As, 0.352 mole of $C_4H_{10}$ react to produce $0.352\times 4=1.41$ moles of $CO_2$

So, the fuel that emitting least amount of $CO_2$ is $C_2H_6$

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