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3 years ago

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If 0.4506 g of KHP standard were titrated with NaOH and the endpoint was reached at 27.96 mL, what is the concentration (molarit

y) of the NaOH solution?

1 answer:

Lemur [1.5K]3 years ago

6 0

Answer is in attachment.

Enjoy :)

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A gene is a region of DNA that encodes function. A chromosome consists of a long strand of DNA containing many genes. A human chromosome can have up to 500 million base pairs of DNA with thousands of genes.

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The tabulated data were collected for this reaction:

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Answer:

ai) Rate law, $Rate = k [CH_3 Cl] [Cl_2]^{0.5}$

aii) Rate constant, k = 1.25

b) Overall order of reaction = 1.5

Explanation:

Equation of Reaction:

$CH_{3} Cl (g) + 3 Cl_2 (g) \rightarrow CCl_4 (g) + 3 HCl (g)$

If $A + B \rightarrow C + D$ , the rate of backward reaction is given by:

$Rate = k [A]^{a} [B]^{b}\\k = \frac{Rate}{ [A]^{a} [B]^{b}}\\k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}}$

k is constant for all the stages

Using the information provided in lines 1 and 2 of the table:

$0.014 / [0.05]^a [0.05]^b = 00.029/ [0.100]^a [0.05]^b\\0.014 / [0.05]^a [0.05]^b = 00.029/ [2*0.05]^a [0.05]^b\\0.014 / = 0.029/ 2^a\\2^a = 2.07\\a = 1$

Using the information provided in lines 3 and 4 of the table and insering the value of a:

$0.041 / [0.100]^a [0.100]^b = 0.115 / [0.200]^a [0.200]^b\\0.041 / [0.100]^a [0.100]^b = 0.115 / [2 * 0.100]^a [2 * 0.100]^b\\$

$0.041 = 0.115 / [2 ]^a [2]^b\\ \[[2 ]^a [2]^b = 0.115/0.041\\ \[[2 ]^a [2]^b = 2.80\\\[[2 ]^1 [2]^b = 2.80\\\[[2]^b = 1.40\\b = \frac{ln 1.4}{ln 2} \\b = 0.5$

The rate law is: $Rate = k [CH_3 Cl] [Cl_2]^{0.5}$

The rate constant $k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}}$ then becomes:

$k = 0.014 / ( [0.050] [0.050]^(0.5) )\\k = 1.25$

b) Overall order of reaction = a + b

Overall order of reaction = 1 + 0.5

Overall order of reaction = 1.5

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<u>Explanation:</u>

Mole fraction is a unit of concentration, defined to be equal to the number of moles of a component divided by the total number of moles of a solution. Because it is a ratio, mole fraction is a unit less expression. The mole fraction of all components of a solution, when added together, will equal 1.

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