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Dafna1 [17]
3 years ago
7

Calculate the value of ΔG°, ΔH°, & ΔS° for the oxidation of solid elemental sulfur to gaseous sulfur trioxide at at 25°C.​2S

(s, rhombic) + 3O2( g) → 2SO3 (g)
Chemistry
1 answer:
Liula [17]3 years ago
4 0

Answer:

ΔG° = -750324.96 J/mol = -750.324 Kj/mol

ΔH° = - 790.4 kJ/mol = -790400 j/mol

ΔS° =  = - 134.48 J K-1mol-1

Explanation:

(S, rhombic) + 3O2( g) → 2SO3 (g)

Temperature = 25°C + 273 = 298K (Converting to kelvin temperature.)

The formulae relating all four paramenters (ΔG°, T, ΔH°, & ΔS°) is given as;

ΔG° = ΔH° - TΔS°

All H and S values used are measurements at 25°C

Calculating ΔH

You started with 1 mole of Sulphur and 3 moles of oxygen.

Total starting enthalpy = 0+ 3(0) = 0 kJ/mol

You ended up with 2 moles of SO3.

Total enthalpy at the end = 2(-395.2) = - 790.4 kJ/mol

enthalpy change = what you end up with - what you started with.

ΔH = enthalpy change =  - 790.4 kJ/mol - 0 kJ/mol = - 790.4 kJ/mol = -790400 j/mol

Calculating ΔS

You started with 1 mole of Sulphur and 3 moles of oxygen.

Total starting entropy =31.88 + 3(205) = 646.88 J K-1mol-1

You ended up with 2 moles of SO3.

Total entropy  at the end = 2(256.2) = 512.4 J K-1mol-1

entropy change = what you end up with - what you started with.

ΔS = entropy change =  512.4 J K-1mol-1 - 646.88 J K-1mol-1

= - 134.48 J K-1mol-1

Inputing the values into the formular, we have;

ΔG° = ΔH° - TΔS°

ΔG° = - 790400 - 298 (- 134.48)

ΔG° =  - 790400 + 40075.04

ΔG° = -750324.96 J/mol = -750.324 Kj/mol

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Consider the following reaction between calcium oxide and carbon dioxide: CaO(s)+CO2(g)→CaCO3(s) A chemist allows 14.4 g of CaO
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Answer:

Theoretical yield =26.03 g

Percent yield = 87%

Limiting reactant = CaO

Explanation:

Given data:

Mass of CaO = 14.4 g

Mass of CO₂ = 13.8 g

Actual yield of CaCO₃ = 22.6 g

Theoretical yield = ?

Percent yield = ?

Limiting reactant = ?

Solution:

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CaO + CO₂   → CaCO₃

Number of moles of CaO:

Number of moles  = Mass /molar mass

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Number of moles  = 0.26 mol

Number of moles of CO₂:

Number of moles = Mass /molar mass

Number of moles = 13.8 g / 44 g/mol

Number of moles = 0.31 mol

Now we will compare the moles of CO₂ and CaO with CaCO₃ .

                  CO₂         :                CaCO₃  

                  1               :                 1

                 0.31           :              0.31

                CaO           :               CaCO₃  

                 1                :                 1

                 0.26         :              0.26

The number of moles of  CaCO₃ produced by CaO are less it will be limiting reactant.

Mass of CaCO₃: Theoretical yield

Mass of CaCO₃ = moles × molar mass

Mass of CaCO₃ =0.26 mol × 100.1 g/mol

Mass of CaCO₃ =  26.03 g

Percent yield:

Percent yield = actual yield / theoretical yield × 100

Percent yield = 22.6 g/ 26.03 g × 100

Percent yield = 0.87× 100

Percent yield = 87%

Limiting reactant:

The number of moles of  CaCO₃ produced by CaO are less it will be limiting reactant.

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