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masya89 [10]
3 years ago
7

Calculate the silver ion concentration in a saturated solution of silver(i) sulfate (ksp = 1.4 × 10–5).

Chemistry
1 answer:
deff fn [24]3 years ago
6 0

Answer:

= 0.030 M

Explanation:

We can take x to be the concentration in mol/L of Ag2SO4 that dissolves  

Therefore;  concentration of  Ag+ is 2x mol/L and that of SO4^2- x mol/L.

Ksp = 1.4 x 10^-5

Ksp = [Ag+]^2 [SO42-]

      = (2x)^2(x)

      = 4x^3  

Thus;

4x^3  = 1.4 x 10^-5

         = 0.015 M

molar solubility = 0.015 M

But;

[Ag+]= 2x

Hence; silver ion concentration is

= 2 x 0.015 M

= 0.030 M

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------------------------------------------------------------------------------------------

2) Molality : It is defined as mole of solute present in Kilogram of solvent . It can be expressed as :

Molality (m) = \frac{mole of solute (mol)}{Kilogram of solvent (Kg)}

Following are the steps to calculate molality :

Step 1: To find mole of Solute :

Mole of solute can be found out using mole formula . It is same as done for molarity .

Mole = 0.0665 mol

Step 2 : To find kilogram of solvent :

Mass of solvent can be calculated using density formula as :

Density \frac{g}{mL} = \frac{mass (g) }{volume (mL)}

Plugging value in density formula :

1.04 \frac{g}{mL}  =  \frac{ mass }{350 mL}

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Mass of solvent = \frac{364 g}{1000g} * 1 Kg

Mass of solvent = 0.364 Kg

Step 3: Plug values of mole and Kg in molality formula :

Molality = \frac{0.0665 mol}{0.364 Kg}

Molality = 0.18 m or 0.18 \frac{mol}{Kg}

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