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jonny [76]
3 years ago
15

When heated, allyl aryl ethers and allyl vinyl ethers undergo a reaction called a Claisen rearrangement, a concerted reorganizat

ion of bonding electrons similar to the Diels-Alder reaction. The reaction proceeds through a six-membered, cyclic transition state.Draw the structure of the expected product when this compound undergoes a Claisen rearrangement.For the purposes of this problem, assume that double bonds in an aromatic ring are localized at the positions indicated in the figure

Chemistry
1 answer:
mario62 [17]3 years ago
8 0

In this case, we assume that the starting compound is phenol which become in phenoxide due to reaction with sodium hydride. Sodium ohenoxide reacts with 3-bromo-1-propene to obtain the allyl aryl ether: allyl phenylether.

The allyl aryl ether undergoes Claisen reanrrangement when is heat between 200 and 250 celsius grades obtaining o-allyl phenol.

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What is the nuclear binding energy of an atom that has a mass defect of 5.0446
notsponge [240]

Answer:

<em>Option C: 4.54 x </em>10^{11}<em> KJ/mol of nuclei</em>

<em>Note: </em>Here in this question option C is not correctly put. It is 4.54 x10^{11} rather than 4.54 x 10^{-123}.

Explanation:

If mass defect is known, then nuclear binding energy can easily be calculated, here's how:

First step is to convert that mass defect into kg.

Mass defect = 5.0446 amu

Mass defect = 5.0466 x 1.6606 x 10^{-27}

Because 1 amu = 1.6606 x 10^{-27} Kg.

<em>Mass defect = 8.383 x </em>10^{-27}<em> kg.</em>

Now, we need to find out it's energy equivalent by using following equation:

Using the equation E = mc²:

where c= 3.00 x 10^{8} m/s²

E = (8.383 x 10^{-27}) x (3.00 x 10^{8})²

E = 7.54 x 10^{-10} J  this energy is in Joules but nuclear binding energy is usually expressed in KJ/mol of nuclei. Let's convert it:

(7.54 x 10^{-10} Joule/nucleus)x(1 kJ/1000 Joule)x(6.022 x 10^{23} nuclei/mol) =  

<em>4.54 x </em>10^{11}<em> kJ/mol of nuclei .</em>

E = <em>4.54 x </em>10^{11}<em> kJ/mol of nuclei .</em> So, this is the nuclear binding energy of that atom, which is option  C.

<em>Note:</em> Here in this question option C is not correctly put. It is 4.54 x10^{11} rather than 4.54 x 10^{-123}

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Which of the following will have the slowest rate of diffusion at a given temperature?
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So diffusion is inversely proportional to mass !
so as mass of the particle increases, diffusion decreases !
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Whats the complete chemical symbol for the ion that has : 13 neutrons 11 protons , and 9 electrons.
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The answer gonna be Na2+
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A sample of neon has a volume of 40.81 m3 at 23.5C. At what temperature, in Kelvins, would the gas occupy 50.00 cubic meters? As
mezya [45]

At  \fbox{\begin \\363 K \end{minispace}}  temperature, a sample of neon gas will occupy 50.00 \text{ m}^{3} volume.

Further Explanation:

The given problem is based on the concept of Charles’ law. Charles’ law states that “at constant pressure and fixed mass the volume occupied an ideal gas is directly proportional to the Kelvin temperature.”

Mathematically the law can be expressed as,

\fbox{ \begin \\ V \propto T \end{minispace}}

Or,

\frac{V}{T}=k

Here, <em>V</em> is the volume of the gas, <em>T</em> is Kelvin temperature, and <em>k</em> is proportionality constant.

Given information:

The initial volume of neon gas is 40.81 \text{ m}^{3} .

The final volume of neon gas is  50.00 \text{ m}^{3}.

The initial temperature value is 23.5 \text{ } ^{\circ} \text{C} .

To calculate:

The final temperature

Given Condition:

  • The pressure is constant.
  • Mass of gas is fixed.

Solution:

Step 1: Modify the mathematical expression for Charles’ law for two different temperature and volume values as follows:

\frac{V_{1}}{T_{1}}=\frac{V_{2}}{T_{2}}

Here,

  • V_{1}is the initial volume of the gas.
  • V_{2} is the final volume of the gas.
  • T_{1} is the initial temperature of the gas.
  • T_{2} is the final temperature of the gas.

Step 2: Rearrange equation (2) for .

\fbox {\begin \\T_{2}=\frac{(V_{2}) \times (T_{1})}{V_{1}}\\\end{minispace}}                                                                  …… (2)

Step 3: Convert the given temperature  from degree Celsius to Kelvin.

The conversion factor to convert degree Celsius to Kelvin is,

T(\text{K}) = T(^{\circ}\text{C}) + 273.15                                      …… (3)

Substitute 23.5\text{ }^{\circ} \text{C} for T(^{\circ}\text{C})  in equation (3) to convert temperature from degree Celsius to Kelvin.

T(\text{K}) = 23.5 \text{ } ^{\circ} \text{C} + 273.15\\T(\text{K})= 296.65 \text{ K}

Step 4: Substitute 40.81 \text{ m}^{3}  for V_{1} ,  50.00 \text{ m}^{3} for V_{2}  and  296.65 \text{ K} for T_{1}  in equation (2) and calculate the value of T_{2} .

T_{2}=\frac{(50.00 \text{ m}^{3}) \times (296.65 \text{ K})}{40.81 \text{ m}^{3}}\\T_{2}=363.45 \text{ K}\\T_{2} \approx 363 \text{ K}

Important note:

  • The temperature must be in Kelvin.
  • The condition of fixed mass and fixed pressure must be fulfilled in order to apply Charles’ law.

Learn More:

1. Gas laws brainly.com/question/1403211

2. Application of Charles’ law brainly.com/question/7434588

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: States of matter

Keywords: neon, volume, occupies, temperature, Kelvin, degree Celsius, Charle’s law, constant pressure, fixed mass, 40.81 m^3 , 50.00 m^3 , 23.5 degree C , celsius , 363 K , sates of matter, initial volume, final volume, initial temperature, final temperature, V1 , V2 , T1 , T2 .

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What is fiber and fabric
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Answer:

Fibre , it is a long thin strand or something like thread of material.

Fabric, it is a cloth material made by weaving or knitting threads together.

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