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olga55 [171]
3 years ago
12

Determine the pH of 0.050 M HCN solution. HCN is a weak acid with a Ka equal to 4.9 x 10-10 DONE

Chemistry
2 answers:
nadezda [96]3 years ago
7 0

Answer:

The pH of the solution is 5.31.

Explanation:

Let "\alpha is the dissociation of weak acid - HCN.

The dissociation reaction of HCN is as follows.

                  HCN+H_{2}O\rightarrow H_{3}O^{+}+CN^{-}

Initial                  C                         0            0

Equilibrium        c(1- \alpha)              c\alpha c\alpha

Dissociation constant = Ka= c\alpha \times \frac{c\alpha}{c(1-\alpha)}

=\frac{c\alpha^{2}}{(1-\alpha)}

In this case weak acids \alpha is very small so, (1-\alpha ) is taken as 1.

Ka=C\alpha^{2}

\alpha=\sqrt\frac{ka}{c}

From the given the concentration = 0.050 M

Substitute the given value.

\alpha=\sqrt\frac{4.9\times 10^{-10}}{0.05}=9.8\times 10^{-4}

[H_{3}O^{+}]=c\alpha

[H_{3}O^{+}]=0.05\times 9.8\times 10^{-4}= 4.9\times10^{-6}

pH= -log[H_{3}O^{+}]

=-log[4.9\times10^{-6}]

=6-log 4.9= 5.31

Therefore, The pH of the solution is 5.31.

MrRissso [65]3 years ago
3 0

Answer:

5.3

The next one is 11

Explanation:

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Need help asap with this chemistry if someone could help me
Burka [1]

Answer:

<h3>1)</h3>

Structure One:

  • N: -2
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Structure Two:

  • N: 0
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Structure Three:

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Structure Number Two would likely be the most stable structure.

<h3>2)</h3>
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The N atom is the one that is "likely" to be attracted to an anion. See explanation.

Explanation:

When calculating the formal charge for an atom, the assumption is that electrons in a chemical bond are shared equally between the two bonding atoms. The formula for the formal charge of an atom can be written as:

\text{Formal Charge} \\ = \text{Number of Valence Electrons in Element} \\ \phantom{=}-\text{Number of Chemical Bonds} \\\phantom{=} - \text{Number of nonbonding Lone Pair Electrons}.

For example, for the N atom in structure one of the first question,

  • N is in IUPAC group 15. There are 15 - 10 = 5 valence electrons on N.
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  • There are three pairs, or 6 electrons that aren't in a chemical bond.

The formal charge of this N atom will be 5 - 1 - 6 = -2.

Apply this rule to the other atoms. Note that a double bond counts as two bonds while a triple bond counts as three.

<h3>1)</h3>

Structure One:

  • N: -2
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Structure Two:

  • N: 0
  • C: 0
  • O: -1

Structure Three:

  • N: -1
  • C: 0
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In general, the formal charge on all atoms in a molecule or an ion shall be as close to zero as possible. That rules out Structure number one.

Additionally, if there is a negative charge on one of the atoms, that atom shall preferably be the most electronegative one in the entire molecule. O is more electronegative than N. Structure two will likely be favored over structure three.

<h3>2)</h3>

Similarly,

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Assuming that electrons in a chemical bond are shared equally (which is likely not the case,) the nitrogen atom in this molecule will carry a positive charge. By that assumption, it would attract an anion.

Note that in reality this assumption seldom holds. In this ion, the N-H bond is highly polarized such that the partial positive charge is mostly located on the H atom bonded to the N atom. This example shows how the formal charge assumption might give misleading information. However, for the sake of this particular problem, the N atom is the one that is "likely" to be attracted to an anion.

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