Which mass of urea, CO(NH2)2, contains the same mass of nitrogen as 101.1g of potassium nitrate?

1 answer:

4 0

In order to calculate the mass of nitrogen, we must first calculate the mass percentage of nitrogen in potassium nitrate. This is:
% nitrogen = mass of nitrogen / mass of potassium nitrate
% nitrogen = 14 / 101.1 x 100

The mass of nitrogen = % nitrogen x sample mass
= (14 / 101.1) x 101.1
= 14 grams

The molar weight of nitrogen is 14. Each mole of urea contains two moles of nitrogen. Therefore, for there to be 14 grams of nitrogen, there must be 0.5 moles of urea.
Mass of urea = moles urea x molecular weight urea
Mass of urea = 0.5 x 66.06
Mass of urea = 33.03 grams

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Construct a three-step synthesis of 1,2-epoxycyclopentane from cyclopentanol by dragging the appropriate formulas into the bins.

zubka84 [21]

Answer:

(1) Bromination, (2) E2 elimination and (3) epoxidation

Explanation:

In the first step, -OH group in cyclopentanol is replaced by more facile leaving group Br by treating cyclopentanol with $PBr_{3}$
In the second step, E2 elimination in presence of strong base e.g. NaOEt/EtOH produce cyclopentene
In the third step, treatment of cyclopentene with mCPBA produces 1,2-epoxycyclopentane
Full reaction scheme has been shown below