Answer:
B)−6,942 J
/mol
Explanation:
At constant temperature and pressure, you cand define the change in Gibbs free energy, ΔG, as:
ΔG = ΔH - TΔS
Where ΔH is enthalpy, T absolute temperature and ΔS change in entropy.
Replacing (25°C = 273 + 25 = 298K; 25.45kJ/mol = 25450J/mol):
ΔG = ΔH - TΔS
ΔG = 25450J/mol - 298K×108.7J/molK
ΔG = -6942.6J/mol
Right solution is:
<h3>B)−6,942 J
/mol</h3>
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Answer:
[OH⁻] = 3.34x10⁻³M; Percent ionization = 0.54%; pH = 11.52
Explanation:
Kb of the reaction:
NH3 + H2O(l) ⇄ NH4+ + OH-
Is:
Kb = 1.8x10⁻⁵ = [NH₄⁺] [OH⁻] / [NH₃]
<em>As all NH₄⁺ and OH⁻ comes from the same source we can write: </em>
<em>[NH₄⁺] = [OH⁻] = X</em>
<em>And as </em>[NH₃] = 0.619M
1.8x10⁻⁵ = [X] [X] / [0.619M]
1.11x10⁻⁵ = X²
3.34x10⁻³ = X = [NH₄⁺] = [OH⁻]
<h3>[OH⁻] = 3.34x10⁻³M</h3><h3 />
% ionization:
[NH₄⁺] / [NH₃] * 100 = 3.34x10⁻³M / 0.619M * 100 = 0.54%
pH:
As pOH = -log [OH-]
pOH = 2.48
pH = 14 - pOH
<h3>pH = 11.52</h3>