Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
![\frac{1}{[A]} =\frac{1}{[A]_0} +kt](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%5Cfrac%7B1%7D%7B%5BA%5D_0%7D%20%2Bkt)
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
![t_{1/2}=\frac{1}{k[A]_0}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B1%7D%7Bk%5BA%5D_0%7D)
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong
Answer:
B. Gravity held the pieces of forming planets together.
c. Gravity pulled most of the matter into the center of the solar system
D. Gravity caused the planets and Sun to have spherical shapes.
Explanation:
When a collection of grains pulled together by their gravitational forces would keep in by the gravity of a star, it would eventually became bigger to the point a planet was formed.
The sun's strong gravitational force pulled most of the matter around it to the center of the solar system.
The spherical shape of planets is a result of their gravity pulling equally from all sides, shaping it into a sphere.
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Explanation:
1. Water decomposition
- Decomposition reactions are represented by-
The general equation: AB → A + B.
- Various methods used in the decomposition of water are -
- Electrolysis
- Photoelectrochemical water splitting
- Thermal decomposition of water
- Photocatalytic water splitting
- Water decomposition is the chemical reaction in which water is broken down giving oxygen and hydrogen.
- The chemical equation will be -

Hence, balancing the equation we need to add a coefficient of 2 in front of
on right-hand-side of the equation and 2 in front of
on left-hand-side of the equation.
∴The balanced equation is -
→ 
2. Formation of ammonia
- The formation of ammonia is by reacting nitrogen gas and hydrogen gas.
→ 
Hence, for balancing equation we need to add a coefficient of 3 in front of hydrogen and 2 in front of ammonia.
∴The balanced chemical equation for the formation of ammonia gas is as follows -
→
.
- When 6 moles of
react with 6 moles of
4 moles of ammonia are produced.
Answer:
400cal
Explanation:
Since ice melted at 0 Celesius then the heat gained by ice (latent heat) will melt it so you should substitute in that law
Q=mlf ..where Q is the heat required to convert ice to water , m is the mass of ice and lf is the latent heat of fusion
Q=5∗80=400cal
Answer:
Number of moles of oxygen = 0.037 mol
Explanation:
Given data:
Total pressure = 98.5 KPa
Partial pressure of nitrogen = 22.0 KPa
Partial pressure of argon = 50.0 KPa
Volume = 3.5 L
Temperature = 25°C (25+273= 298K)
Number of moles of oxygen = ?
Solution:
Total pressure = P(N₂) + P(O₂) + P(Ar)
98.5 KPa = 22.0 KPa +P(O₂) + 50.0 KPa
98.5 KPa = 72.0 KPa +P(O₂)
P(O₂) = 98.5 KPa - 72.0 KPa
P(O₂) = 26.5 KPa
KPa to atm:
26.5 KPa/ 101 = 0.262 atm
Number of moles of oxygen:
PV = nRT
n = PV/RT
n = 0.262 atm × 3.5 L / 0.0821 atm.L/mol.K × 298 K
n = 0.917atm.L /24.47atm.L/ mol
n = 0.037 mol