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lubasha [3.4K]
3 years ago
11

When you decrease the volume of a gas, what happens to the temperature?

Chemistry
1 answer:
ale4655 [162]3 years ago
4 0

the temperature is decreased

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Atoms cannot physically get more compact (temperature lowering increases the space between atoms) At absolute zero, the atoms are as physically close together as allowed by the physical laws governing it.
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Which is always the first step in dealing with an accident in the lab?
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Thermal energy can be transformed to do work .<br> true<br> false
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FALSE!!! Thermal energy can be transformed to heat.

Explanation:

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How could an increase in industrial activity in developing nations contribute to global climate change?
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The reaction described by H2(g)+I2(g)⟶2HI(g) has an experimentally determined rate law of rate=k[H2][I2] Some proposed mechanism
MatroZZZ [7]

Answer:

Mechanism A and B are consistent with observed rate law

Mechanism A is consistent with the observation of J. H. Sullivan

Explanation:

In a mechanism of a reaction, the rate is determinated by the slow step of the mechanism.

In the proposed mechanisms:

Mechanism A

(1) H2(g)+I2(g)→2HI(g)(one-step reaction)

Mechanism B

(1) I2(g)⇄2I(g)(fast, equilibrium)

(2) H2(g)+2I(g)→2HI(g) (slow)

Mechanism C

(1) I2(g) ⇄ 2I(g)(fast, equilibrium)

(2) I(g)+H2(g) ⇄ HI(g)+H(g) (slow)

(3) H(g)+I(g)→HI(g) (fast)

The rate laws are:

A: rate = k₁ [H2] [I2]

B: rate = k₂ [H2] [I]²

As:

K-1 [I]² = K1 [I2]:

rate = k' [H2] [I2]

<em>Where K' = K1 * K2</em>

C: rate = k₁ [H2] [I]

As:

K-1 [I]² = K1 [I2]:

rate = k' [H2] [I2]^1/2

Thus, just <em>mechanism A and B are consistent with observed rate law</em>

In the equilibrium of B, you can see the I-I bond is broken in a fast equilibrium (That means the rupture of the bond is not a determinating step in the reaction), but in mechanism A, the fast rupture of I-I bond could increase in a big way the rate of the reaction. Thus, just <em>mechanism A is consistent with the observation of J. H. Sullivan</em>

5 0
3 years ago
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