How many values of these of these trials can be considered accurate?

What factors should be taken into consideration when choosing the ideal solvent for the crystallization of a particular compound

never [62]

Answer: the following are essential factors to be considered when choosing a solvent for crystallization

1. The crystallization solvent should not dissolve the substance to be purified at room temperature, but it should dissolve it well at the solvent’s boiling point

2. The solvent should dissolve soluble impurities well at room temperature.

3. The solvent should not dissolve insoluble impurities even at the solvent’s boiling point.

4. The solvent must not react with the substance to be purified .

3 0

3 years ago

Which of the compounds above are strong enough acids to react almost completely with a hydroxide ion (pka of h2o = 15.74) or wit

luda_lava [24]

The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Further explanation </em></h3>

In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)

Acids and bases according to Bronsted-Lowry

Acid = donor (donor) proton (H + ion)

Base = proton (receiver) acceptor (H + ion)

If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.

From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.

The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant

Can be formulated:

K acid-base reaction = Ka acid on the left : K acid on the right.

or:

pK = acid pKa on the left - pKa acid on the right

K = equilibrium constant for acid-base reactions

pK = -log K;

$K~=~10^{-pK}$

K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.

There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:

pyridinium pKa = 5.25

acetone pKa = 19.3

butan-2-one pKa = 19

Let's look at the K value of each possible reaction:

pka H₂O = 15.74, pka of H₂CO₃ = 6.37)

1. C₅H₆N pyridinium

* with OH⁻

C₅H₆N + OH- ---> C₅H₅N- + H₂O

pK = pKa pyridinium - pKa H₂O

pK = 5.25 - 15.74

pK = -10.49

$K~=~10^{4.9}$

K values> 1 indicate the reaction can take place

* with HCO3⁻

C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃

pK = 5.25 - 6.37

pK = -1.12

$K`=~10^{1.12]$

Reaction can take place

2. Acetone C₃H₆O

* with OH-

C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O

pK = 19.3 - 15.74

pK = 3.56

$K~=~10^{ -3.56}$

Reaction does not happen

* with HCO₃-

C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃

pK = 19.3 - 6.37

pK = 12.93

$K`=~10 ^{-12.93}$

Reaction does not happen

3. butan-2-one C₄H₇O

* with OH-

C₄H₇O + OH- ---> C₄H₆O- + H₂O

pK = 19 - 15.74

pK = 3.26

$K~=~10^{-3.26}$

Reaction does not happen

* with HCO₃⁻

C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃

pK = 19 - 6.37

pK = 12.63

$K~=~ 10^{-12.63}$

Reaction does not happen

So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Learn more </em></h3>

the lowest ph

brainly.com/question/9875355

the concentrations at equilibrium.

brainly.com/question/8918040

the ph of a solution

brainly.com/question/9560687

Keywords : acid base reaction, the equilibrium constant

5 0

3 years ago

Read 2 more answers

When should you<br> use a fume hood?

AfilCa [17]

Answer:

if you are working with hazardous materials.

Explanation:

A properly operating and correctly used fume hood can reduce or eliminate exposure to volatile liquids, dusts, and mists. It is advisable to use a laboratory hood when working with all hazardous substances.

4 0

4 years ago

Consider a voltaic cell where the anode half-reaction is Zn(s) → Zn2+(aq) + 2 e− and the cathode half-reaction is Sn2+(aq) + 2 e

notsponge [240]

<u>Answer:</u> The concentration of $Sn^{2+}$ in the cell is $9.0\times 10^{-3}M$

<u>Explanation:</u>

We are given:

<u>Oxidation half reaction:</u> $Zn(s)\rightarrow Zn^{2+}(aq.)+2e^-$ $E^o_{Zn^{2+}/Zn}=-0.76V$

<u>Reduction half reaction:</u> $Sn^{2+}(aq.)+2e^-\rightarrow Sn(s)$ $E^o_{Sn^{2+}/Sn}=-0.136V$

The substance having highest positive $E^o$ potential will always get reduced and will undergo reduction reaction. Here, fluorine will undergo reduction reaction will get reduced.

Here, tin will undergo reduction reaction and will get reduced.

Oxidation reaction occurs at anode and reduction reaction occurs at cathode.

To calculate the $E^o_{cell}$ of the reaction, we use the equation:

$E^o_{cell}=E^o_{cathode}-E^o_{anode}$

Putting values in above equation, we get:

$E^o_{cell}=-0.136-(-0.76)=0.624V$

To calculate the EMF of the cell, we use the Nernst equation, which is:

$E_{cell}=E^o_{cell}-\frac{0.059}{n}\log \frac{[Mn^{2+}]}{[Cu^{2+}]}$

where,

$E_{cell}$ = electrode potential of the cell = 0.660 V

$E^o_{cell}$ = standard electrode potential of the cell = +0.624 V

n = number of electrons exchanged = 2

$[Zn^{2+}]=2.5\times 10^{-3}M$

$[Sn^{2+}]$ = ?

Putting values in above equation, we get:

$0.660=0.624-\frac{0.059}{2}\times \log(\frac{2.5\times 10^{-3}}{[Sn^{2+}})$

$[Sn^{2+}]=9.0\times 10^{-3}M$

Hence, the concentration of $Sn^{2+}$ ions is $9.0\times 10^{-3}M$

3 0

3 years ago

Calculate the formula unit mass of CaCl2

melomori [17]

Formula unit mass is defined as the sum of the mass of all the atoms each multiplied its atomic masses that are present in the empirical formula of a compound. It is expressed in amu.

Atomic mass of calcium = 40 amu

Atomic mass of chlorine = 35.5 amu

Formula mass of CaCl2 = (1 x 40) + (2 x 35.5) = 111amu.

3 0

3 years ago