The free energy change of the reaction; Fe (s) + Au3+ (aq) -> Fe3+ (aq) + Au (s) is calculated to be -443.83KJ/mol.
For the reaction shown in question 7, we can divide it into half equations as follows;
Oxidation half equation;
6 Al (s) -------> 6Al^3+(aq) + 18e
Reduction half equation;
3Cr2O7^2-(aq) + 42H^+(aq) + 18e -----> 6Cr^3+(aq) + 21H2O(l)
The balanced reaction equation is;
6Al(s) + 3Cr2O7^2-(aq) + 42H^+(aq) -----> 6Al^3+(aq) + 6Cr^3+(aq) + 21H2O(l)
The E° of this reaction is obtained from;
E° anode = -0.04 V
E°cathode = +1.50 V
E° cell = +1.50 V - (-0.04 V) = 1.54 V
Given that;
ΔG° = -nFE°cell
n = 3, F = 96500, E°cell = 1.54 V
ΔG° = -(3 × 96500 × 1.54)
ΔG° = -443.83KJ/mol
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I think its answer choice A because it would better to talk to their parents first and not take matters into your own hands.
Answer:
- Mass of monobasic sodium phosphate = 1.857 g
- Mass of dibasic sodium phosphate = 1.352 g
Explanation:
<u>The equilibrium that takes place is:</u>
H₂PO₄⁻ ↔ HPO₄⁻² + H⁺ pka= 7.21 (we know this from literature)
To solve this problem we use the Henderson–Hasselbalch (<em>H-H</em>) equation:
pH = pka + ![log\frac{[A^{-} ]}{[HA]}](https://tex.z-dn.net/?f=log%5Cfrac%7B%5BA%5E%7B-%7D%20%5D%7D%7B%5BHA%5D%7D)
In this case [A⁻] is [HPO₄⁻²], [HA] is [H₂PO₄⁻], pH=7.0, and pka = 7.21
If we use put data in the <em>H-H </em>equation, and solve for [HPO₄⁻²], we're left with:
![7.0=7.21+log\frac{[HPO4^{-2} ]}{[H2PO4^{-} ]}\\ -0.21=log\frac{[HPO4^{-2} ]}{[H2PO4^{-} ]}\\\\10^{-0.21} =\frac{[HPO4^{-2} ]}{[H2PO4^{-} ]}\\0.616 * [H2PO4^{-}] = [HPO4^{-2}]](https://tex.z-dn.net/?f=7.0%3D7.21%2Blog%5Cfrac%7B%5BHPO4%5E%7B-2%7D%20%5D%7D%7B%5BH2PO4%5E%7B-%7D%20%5D%7D%5C%5C%20-0.21%3Dlog%5Cfrac%7B%5BHPO4%5E%7B-2%7D%20%5D%7D%7B%5BH2PO4%5E%7B-%7D%20%5D%7D%5C%5C%5C%5C10%5E%7B-0.21%7D%20%3D%5Cfrac%7B%5BHPO4%5E%7B-2%7D%20%5D%7D%7B%5BH2PO4%5E%7B-%7D%20%5D%7D%5C%5C0.616%20%2A%20%5BH2PO4%5E%7B-%7D%5D%20%3D%20%5BHPO4%5E%7B-2%7D%5D)
From the problem, we know that [HPO₄⁻²] + [H₂PO₄⁻] = 0.1 M
We replace the value of [HPO₄⁻²] in this equation:
0.616 * [H₂PO₄⁻] + [H₂PO₄⁻] = 0.1 M
1.616 * [H₂PO₄⁻] = 0.1 M
[H₂PO₄⁻] = 0.0619 M
With the value of [H₂PO₄⁻] we can calculate [HPO₄⁻²]:
[HPO₄⁻²] + 0.0619 M = 0.1 M
[HPO₄⁻²] = 0.0381 M
With the concentrations, the volume and the molecular weights, we can calculate the masses:
- Molecular weight of monobasic sodium phosphate (NaH₂PO₄)= 120 g/mol.
- Molecular weight of dibasic sodium phosphate (Na₂HPO₄)= 142 g/mol.
- mass of NaH₂PO₄ = 0.0619 M * 0.250 L * 120 g/mol = 1.857 g
- mass of Na₂HPO₄ = 0.0381 M * 0.250 L * 142 g/mol = 1.352 g
Answer:
7.68 × 10²⁴
Explanation:
Step 1: Calculate the mass of 1 molecule of the monomer CH₂CHCN
We will get the mass of the monomer by adding the masses of the elements.
mCH₂CHCN = 3 × mC + 3 × mH + 1 × mN
mCH₂CHCN = 3 × 12.01 amu + 3 × 1.01 amu + 1 × 14.01 amu = 53.07 amu
Step 2: Convert the mass of the monomer to grams
We will use the conversion factor 1 amu = 1.66 × 10⁻²⁴ g
53.07 amu × 1.66 × 10⁻²⁴ g/1 amu = 8.81 × 10⁻²³ g
Step 3: Calculate "n"
We will divide the mass of the polymer by the mass of the monomer.
n = 676.8 g / 8.81 × 10⁻²³ g = 7.68 × 10²⁴
Explanation:
47.0g is the mass of ammonia