State Hund’s rule in your own words, and show its application in the orbital diagram of the nitrogen atom.
1 answer:
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Answer:
The structure of the salt is attached.
Explanation:
Physostigmine, an alkaloid obtained from a West African plant (Physotigma venenosum),is used in the treatment of glaucoma. Treatment of physostigmine with methyl iodide gives a quaternary ammonium salt. What is the structure of this salt?
The structure of the salt is attached
Answer:
a. 3-methylbutan-2-ol
b. 2-methylcyclohexan-1-ol
Explanation:
For this reaction, we must remember that the hydroboration is an <u>"anti-Markovnikov" reaction</u>. This means that the "OH" will be added at the <em>least substituted carbon of the double bond.</em>
In the case of <u>2-methyl-2-butene</u>, the double bond is between carbons 2 and 3. Carbon 2 has two bonds with two methyls and carbon 3 is attached to 1 carbon. Therefore <u>the "OH" will be added to carbon three</u> producing <u>3-methylbutan-2-ol</u>.
For 1-methylcyclohexene, the double bond is between carbons 1 and 2. Carbon 1 is attached to two carbons (carbons 6 and 7) and carbon 2 is attached to one carbon (carbon 3). Therefore<u> the "OH" will be added to carbon 2</u> producing <u>2-methylcyclohexan-1-ol</u>.
See figure 1
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