Longer, this is because the H in HNO2 is bonded with an oxygen, no longer allowing this structure to have a resonance structure.
NO2 on the other hand has one double bond and one single bond, so it has a resonance structure. And resonance structures are actually one structure so there isn't really a single and double bond, it's actually a 1 and 1/2 bond that calls for a higher bond order.
And I higher bond order will result in a shorter lengths!
I hope this helps out!!! And just out of curiosity, is this off of an AP FRQ packet??
Look at the periodic table to find the charge on atoms.
Magnesium is +2 and Nitrogen is -3. Since there are two nitrogen charge 2*-3 = -6 there needs to be 3 Mg then (3*2+ = 6+) to pair with the two nitrogen.
3 Mg(+2) + 2 N(-3) = Mg3N2
C) It determines the concentration of an unknown substance in neutralization reactions.