Answer: Rate law=
, order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is 
Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
![Rate=k[A]^x[B]^y](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5Ex%5BB%5D%5Ey)
k= rate constant
x = order with respect to A
y = order with respect to A
n = x+y = Total order
a) From trial 1:
(1)
From trial 2:
(2)
Dividing 2 by 1 :![\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%7B1.2%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.20%5D%5Ey%7D)
therefore y=2.
b) From trial 2:
(3)
From trial 3:
(4)
Dividing 4 by 3:![\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B9.6%5Ctimes%2010%5E%7B-2%7D%7D%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.20%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D)
, x=1
Thus rate law is ![Rate=k[A]^1[B]^2](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5E1%5BB%5D%5E2)
Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.
c) For calculating k:
Using trial 1: ![1.2\times 10^{-2}=k[0.10]^1[0.20]^2](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5E1%5B0.20%5D%5E2)
.
Answer:
Both diseases affect the control of voluntary muscles.
Explanation:
Parkinson's disease is a progressive brain disease that affects movement. It affects the nerve cells that produce dopamine in the part of the brain called substantia nigra. The symptoms include shaking, stiffness, and difficulty with walking, balance, and coordination. Symptoms get worse with time, often leaving people with difficulty walking and talking.
ALS (amyotrophic lateral sclerosis) is a progressive nervous system disease that affects nerve cells in the brain and spinal cord. The first symptoms usually involve muscle weakness, and as the disease progresses, it results in the loss of muscle control.
Scientists don't know the exact cause of these diseases. As the cause is not known, there is no exact way to prevent them. There is no cure for them, either. The treatment is focused on the management of symptoms.
This is why the third option is the correct one.
We will use boiling point formula:
ΔT = i Kb m
when ΔT is the temperature change from the pure solvent's boiling point to the boiling point of the solution = 77.85 °C - 76.5 °C = 1.35
and Kb is the boiling point constant =5.03
and m = molality
i = vant's Hoff factor
so by substitution, we can get the molality:
1.35 = 1 * 5.03 * m
∴ m = 0.27
when molality = moles / mass Kg
0.27 = moles / 0.015Kg
∴ moles = 0.00405 moles
∴ The molar mass = mass / moles
= 2 g / 0.00405 moles
= 493.8 g /mol
Answer:
[KOH] = 0.10M in KOH
Explanation:
Molar Concentration [M] = moles solute/volume solution in liters
moles KOH = 0.56g/56g/mole = 0.01mole
Volume of solution = 100cm³ = 100ml = 0.10 liter
[KOH] = 0.01 mole KOH / 0.10 liter solution = 0.10M in KOH