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Xelga [282]
3 years ago
11

When calculating the equilibrium constant, aqueous solutes must be expressed in moles per liter (M), and gases must be expressed

in pressure as bars. This is because___________.a. there are no other ways to express pressure or concentration other than bars or moles per liter (M). b. they are dimensionless ratios of the actual concentration or pressure divided by standard state concentration, which is 1 M for solutions and 1 bar for gases.c. these are the only units of concentration and pressure that are independent of temperature.d. the dimensionless ratios are always unity (1) because the concentration of the solute or pressure of the gas are divided by standard state concentrations.
Chemistry
1 answer:
alukav5142 [94]3 years ago
3 0

Answer:

B. They are dimensionless ratios of the actual concentration or pressure divided by standard state concentration, which is 1 M for solutions and 1 bar for gases.

Explanation:

Activity of a substance is defined as the ratio of an effective concentration or an effective pressure to a standard state pressure or a standard state pressure. It is usually a unit less ratio.

Concentrations in an equilibrium constant are really dimensionless ratios of actual concentrations divided by standard state concentrations. Since standard states are 1 M for solutes, 1 bar for gases, and pure substances for solids and liquids, these are the units to be used.

Hence, activity is a fudge factor to ideal solutions that correct the true concentration. Activity of a gas and solute concentration is a ratio with no unit.

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LenKa [72]

Answer: 23 g

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the mol of CO is \frac{2,63.10^{24} }{6.10^{23} }= \frac{263}{60} (mol)

we have:

Fe2O3 + 3CO => 2Fe + 3CO2

23/112    69/112     23/56

=> the mol of Fe is 23/56 mol

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Explanation:

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Nimfa-mama [501]
The enthalpy energy in condensation process is negative because it releases energy
The entropy in  will also decreases .
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The decomposition of NI3 to form N2 and I2 releases −290.0 kJ of energy. The reaction can be represented as 2NI3(s)→N2(g)+3I2(g)
EastWind [94]

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-7.34 kilo Joules is the change in enthaply when 20.0 grams of nitrogen triiodide decomposes.

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Moles of nitrogen triiodide = \frac{20.0 g}{395 g/mol}=0.05063 mol

2NI_3(s)\rightarrow N_2(g)+3I_2(g), \Delta H_{rxn}=-290.0 kJ

According to reaction, 2 moles of nitrogen triiodide gives 290.0 kilo Joules of heat on decomposition ,then 0.05063 moles of nitrogen triiodide will give :

\frac{-290.0 kJ}{2}\times 0.05063=-7.34 kJ

-7.34 kilo Joules is the change in enthaply when 20.0 grams of nitrogen triiodide decomposes.

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3 years ago
Silver occurs in trace amounts in some ores of lead, and lead can displace silver from solution: Pb(s) + 2Ag+ (aq) LaTeX: \longr
VikaD [51]

Answer : The value of \Delta G^o and K is, -180 kJ/mol and 3.6\times 10^{31}

Explanation :

The balanced cell reaction will be,

Pb(s)+2Ag^+(aq)\rightarrow Pb^{2+}(aq)+2Ag(g)

The half-cell reactions are:

Oxidation reaction (anode) : Pb(s)\rightarrow Pb^{2+}(aq)+2e^-

Reduction reaction (cathode) : 2Ag^+(aq)+2e^-\rightarrow 2Ag(g)

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}

where,

\Delta G^o = standard Gibbs free energy

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n = number of electrons in oxidation-reduction reaction = 2

E^o_{cell} = standard electrode potential of the cell = 0.93 V

Now put all the given values in the above formula, we get:

\Delta G^o=-2\times 96500\times 0.93

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Now we have to calculate the value of 'K'.

\Delta G^o=-RT\ln K

where,

\Delta G_^o =  standard Gibbs free energy  = -180 kJ/mol

R = gas constant = 8.314\times 10^{-3}kJ/mole.K

T = temperature = 298 K

K = equilibrium constant = ?

Now put all the given values in the above formula 1, we get:

-180kJ/mol=-(8.314\times 10^{-3}kJ/mole.K)\times (298K)\times \ln K

K=3.6\times 10^{31}

Therefore, the value of \Delta G^o and K is, -180 kJ/mol and 3.6\times 10^{31}

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