The enthalpy change of the reaction below (ΔHr×n , in kJ) using the bond energies provided. CO(g) + Cl₂(g) → Cl₂CO(g). is - 108kJ.
The bond energies data is given as follows:
BE for C≡O = 1072 kJ/mol
BE for Cl-Cl = 242 kJ/mol
BE for C-Cl = 328 kJ/mol
BE for C=O = 766 kJ/mol
The enthalpy change for the reaction is given as :
ΔHr×n = ∑H reactant bond - ∑H product bond
ΔHr×n = ( BE C≡O + BE Cl-Cl) - ( BE C=O + BE 2 × Cl-Cl )
ΔHr×n = ( 1072 + 242 ) - ( 766 + 656 )
ΔHr×n = 1314 - 1422
ΔHr×n = - 108 kJ
Thus, The enthalpy change of the reaction below ( ΔHr×n , in kJ) using the bond energies provided. CO(g) + Cl₂(g) → Cl₂CO(g). is - 108kJ.
To learn more about enthalpy here
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Electronegativity of an element decreases as we move down a group on the periodic table and electronegativity increases while moving from left to right across a period on the periodic table.
Explanation:
- The electronegativity increases as we move from left to right across a period because from left to right across a period, the nuclear charge is increasing Hence the attraction for the valence electrons also increases.
- As we move down a group, the atoms of each element have an increasing number of energy levels. The distance between the nucleus and valence electron shell increases and reduces the attraction for valence electrons. Hence electronegativity decreases as we move from top to bottom down a group.
Answer: 39 electrons
Explanation: Subtract 79 by 40 to get the atomic number (amount of protons) which is 39. The number of electrons must be the same as the number of protons if it's not an ionic compound so the amount of electrons is the same amount of protons.
The rate law equation for Ozone reaction
r=k[O][O₂]
<h3>Further e
xplanation</h3>
Given
Reaction of Ozone :.
O(g) + O2(g) → O3(g)
Required
the rate law equation
Solution
The rate law is a chemical equation that shows the relationship between reaction rate and the concentration / pressure of the reactants
For reaction
aA + bB ⇒ C + D
The rate law can be formulated:
![\large{\boxed{\boxed{\bold{r~=~k.[A]^a[B]^b}}}](https://tex.z-dn.net/?f=%5Clarge%7B%5Cboxed%7B%5Cboxed%7B%5Cbold%7Br~%3D~k.%5BA%5D%5Ea%5BB%5D%5Eb%7D%7D%7D)
where
r = reaction rate, M / s
k = constant, mol¹⁻⁽ᵃ⁺ᵇ⁾. L⁽ᵃ⁺ᵇ⁾⁻¹. S⁻¹
a = reaction order to A
b = reaction order to B
[A] = [B] = concentration of substances
So for Ozone reaction, the rate law (first orde for both O and O₂) :
![\tt \boxed{\bold{r=k[O][O_2]}}](https://tex.z-dn.net/?f=%5Ctt%20%5Cboxed%7B%5Cbold%7Br%3Dk%5BO%5D%5BO_2%5D%7D%7D)