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serious [3.7K]
3 years ago
9

You wish to prepare a buffer consisting of acetic acid and sodium acetate with a total acetic acetate plus acetate concentration

of 250 mm and a ph of 5. what concentrations of acetic acid and sodium acetate should you use
Chemistry
1 answer:
vovangra [49]3 years ago
7 0

<u>Ans: Acetic acid = 90.3 mM and Sodium acetate = 160 mM</u>

Given:

Acetic Acid/Sodium Acetate buffer of pH = 5.0

Let HA = acetic acid

A- = sodium acetate

Total concentration [HA] + [A-] = 250 mM ------(1)

pKa(acetic acid) = 4.75

Based on Henderson-Hasselbalch equation

pH = pKa + log[A-]/[HA]

[A-]/[HA] = 10^(pH-pKa) = 10^(5-4.75) = 10^0.25 = 1.77

[A-] = 1.77[HA] -----(2)

From (1) and (2)

[HA] + 1.77[HA] = 250 mM

[HA] = 250/2.77 = 90.25 mM

[A-] = 1.77(90.25) = 159.74 mM



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3 0
3 years ago
Read 2 more answers
1. john needs to create a buffered solution at a ph of 3.5 for his biomedical laboratory
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Answer:

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Explanation:

John could prepare a lactate buffer.

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\text{pH} = \text{pK}_{\text{a}} + \log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}}\\\\3.5 = 3.86 + \log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}}\\\\\log\dfrac{\text{[A$^{-}$]}}{\text{[HA]}} = 3.5 - 3.86 = -0.36\\\\\dfrac{\text{[A$^{-}$]}}{\text{[HA]}} = 10^{-0.36} = \mathbf{0.44}

He should use a ratio of 0.44 mol lactate to 1 mol of lactic acid.

For example, he could mix equal volumes of 0.044 mol·L⁻¹ lactate and 0.1 mol·L⁻¹ lactic acid.

6 0
3 years ago
One and a half gallons of paint are used on refrigeration units which are then baked dry in a 275F oven for 2 hours. If the pain
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Explanation:

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95% of 1.5 gallon=(95/100)*1.5 = 1.425 gallons.

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So 1.425 gallons=8*1.425 pints

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Evaporation requires 2 hours. That is 3600*2 seconds = 7200 seconds.

So evaporation rate= 11.4 pints/7200 seconds.

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Explanation:

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