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8_murik_8 [283]
2 years ago
6

The chemical shift of the CH3 protons in diethylether is δ = 1.16 and that of the CH2 protons is 3.36. What is the difference in

local magnetic field between the two regions of the molecule when the applied field is (a) 1.9T, (b) 16.5 T?
Chemistry
1 answer:
grandymaker [24]2 years ago
5 0

Answer:

Where Blocal = local magnetic field between the two regions of the molecule

Blocal = (1-σ)B0

ΔBlocal = (1-σ1)B0 - (1-σ2)B0 = (σ2 - σ1)B0 = ΔσB0 ≈ ΔδB0 x 10∧-6

= (3.36-1.16) x 10∧-6 x B0 = 2.20 x 10∧-6B0

(a) ΔBlocal = 2.20 x 10∧-6 x 1.9T = 4.2 μT

(b) ΔBlocal = 2.20 x 10∧-6 x 16.5T = 36.3 μT

Explanation:

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When 6.040 grams of a hydrocarbon, CxHy, were burned in a combustion analysis apparatus, 18.95 grams of CO2 and 7.759 grams of H
algol [13]

Answer: The empirical formula is CH_2 and molecular formula is C_4H_8

Explanation:

We are given:

Mass of CO_2 = 18.95 g

Mass of H_2O= 7.759 g

Molar mass of carbon dioxide = 44 g/mol

Molar mass of water = 18 g/mol

For calculating the mass of carbon:

In 44g of carbon dioxide, 12 g of carbon is contained.

So, in 18.59 g of carbon dioxide, =\frac{12}{44}\times 18.59=5.07g of carbon will be contained.

For calculating the mass of hydrogen:

In 18g of water, 2 g of hydrogen is contained.

So, in 7.759 g of water, =\frac{2}{18}\times 7.759=0.862g of hydrogen will be contained.

Mass of C = 5.07 g

Mass of H = 0.862 g

Step 1 : convert given masses into moles.

Moles of C =\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{5.07g}{12g/mole}=0.422moles

Moles of H=\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{0.862g}{1g/mole}=0.862moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C =\frac{0.422}{0.422}=1

For H =\frac{0.862}{0.422}=2

The ratio of C : H = 1: 2

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The empirical weight of CH_2 = 1(12)+2(1)= 14 g.

The molecular weight = 56.1 g/mole

Now we have to calculate the molecular formula.

n=\frac{\text{Molecular weight }}{\text{Equivalent weight}}=\frac{56.1}{14}=4

The molecular formula will be=4\times CH_2=C_4H_8

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3 years ago
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3 years ago
above shows a balloon full of gas which has a volume of 120.0ml at 300.0k assuming pressure remains constant , what is the voume
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Explanation:

given that:

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