Answer:
Creating vacancies in ceramics. Consider doping ZrO₂ with small concentrations of Nb205. The valence of Nb is 5. Assume that Nb ions sit in Zr ion sites
a. A substitutional defect will be produced.
b. With this dopping, the Nb increases electron band conduction and decreases oxygen anion conduction in ZrO₂.
Explanation:
(a) The defect produced by dopping a little concentration of Nb₂O5 with Nb in the +5 charge state is known as a substitutional defect.
(b) With this dopping, the Nb increases electron band conduction and decreases oxygen anion conduction in ZrO₂.
Moreover, if oxygen vacancies are rate-limiting defect, the corrosion of ZrO₂ decreases and if electrons are rate-limiting then the corrosion of ZrO₂ is accelerated.
Answer:
a. Fraction of Atom = 2.41E-5 when T = 600K
b. Fraction of Atom = 5.03E-10 when T = 298K
Explanation:
a.
Given
T = Temperature = 600K
Qv = Energy for formation = 0.55eV/atom
To calculate the fraction of atom sites, we make use of the following formula
Nv/N = exp(-Qv/kT)
Where k = Boltzmann Constant = 8.62E-5eV/K
Nv/N = exp(-0.55/(8.62E-5 * 600))
Nv/N = 0.000024078672493307
Nv/N = 2.41E-5
b. When T = 298K
Nv/N = exp(-0.55/(8.62E-5 * 298))
Nv/N = 5.026591237904E−10
Nv/N = 5.03E-10 ----- Approximated
Answer:orientation of piles
Explanation:
The stiffness and strength of a properly constructed composite buildup depend upon the orientation of piles to the load direction.
Structural composite materials are designed and manufactured to withstand certain specific stress loads. The ability to withstand these stress loads depends, to a large extent, on how the fibers are arranged. The fiber orientation of the parts must be the same as that of the original form.