The question seems to be expecting a comparative answer.
Let us consider Scenario 1 first.
We have the variables listed as follows:
Initial Velocity
= v m/s
Final Velocity
= 0, since the car is stopping.
Acceleration = - a
, since the car is slowing down.
Let the stopping distance in this case be S
We can arrive at the expression for S by using the equation 
Plugging in what we know, we get 
Hence, stopping distance in Scenario 1 is 
Now, considering Scenario 2, we have
Initial Velocity
= 5v m/s
Final Velocity
= 0
Acceleration = - a
, since it is given to be same in both the cases.
Let the stopping distance this time be 
We can use the same equation for this scenario too, i.e. 
Plugging in what we have, we get 
Solving this for
, we get 
This can be written in terms of S as 
Thus, the car's new stopping distance will be 25 times compared to the older one!