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grandymaker [24]
3 years ago
14

A mass of 2 kg of acetylene is in a 0.045 m3 rigid container at a pressure of 4.3 MPa. Use the generalized charts to estimate th

e temperature.
Chemistry
1 answer:
sattari [20]3 years ago
5 0

Answer:

361 K

Explanation:

From the tables:

P_r=4.3/6.14=0.7,T_c=308.3\ K, R=0.2193\ kJ/kgK\\\\Volume (V)=0.045m^3, mass(m)=2kg\\\\v=V/m=0.045/2=0.0225\ m^3/kg

Given that:

v=\frac{ZRT}{P}

From the charts, at P_r=0.7,Z_g=0.59,T_r=0.94

v_g=\frac{0.59*0.3193*0.94*308.3}{4300}=0.0127\ m^3/kg\ which\ is\ small\\ \\At\ T_r=1,Z=0.7,v=\frac{0.7*0.3193*1*308.3}{4300}=0.016\ m^3/kg\\\\At\ T_r=1.2,Z=0.86,v=\frac{0.86*0.3193*1.2*308.3}{4300}=0.0236\ m^3/kg

Interpolating, we get T_r=1.17, T = 361 K

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Given the following thermodynamic data, calculate the lattice energy of LiCl:
tiny-mole [99]

Answer:

\boxed{\text{-862 kJ/mol}}

Explanation:

One way to calculate the lattice energy is to use Hess's Law.

The lattice energy U is the energy released when the gaseous ions combine to form a solid ionic crystal:

Li⁺(g) + Cl⁻(g) ⟶ LiCl(s); U = ?

We must generate this reaction rom the equations given.

(1)  Li(s) + ½Cl₂ (g) ⟶ LiCl(s);      ΔHf°     = -409 kJ·mol⁻¹

(2) Li(s) ⟶ Li(g);                          ΔHsub =    161 kJ·mol⁻¹

(3) Cl₂(g) ⟶ 2Cl(g)                     BE        =   243 kJ·mol⁻¹

(4) Li(g) ⟶Li⁺(g) +e⁻                   IE₁         =   520 kJ·mol⁻¹

(5) Cl(g) + e⁻ ⟶ Cl⁻(g)                EA₁       =  -349 kJ·mol⁻¹

Now, we put these equations together to get the lattice energy.

                                                <u>E/kJ </u> 

(5) Li⁺(g) +e⁻ ⟶ Li(g)                520

(6) Li(g) ⟶ Li(s)                         -161

(7) Li(s) + ½Cl₂(g) ⟶ LiCl(s)     -409

(8) Cl(g) ⟶ ½Cl₂(g)                   -121.5

(9) Cl⁻(g) ⟶ Cl(g) + e⁻               <u>+349</u>

      Li⁺(g) +  Cl⁻(g) ⟶ LiCl(s)     -862

The lattice energy of LiCl is \boxed{\textbf{-862 kJ/mol}}.

3 0
3 years ago
Hurry!! Please
Vanyuwa [196]

c

Explanation:

pay attention in class next time bye hope it helps THE ANSWER IS C bye

7 0
2 years ago
A compound containing chromium, Cr; chlorine, Cl; and oxygen, O, is analyzed and found to be 33.6% chromium, 45.8% chlorine, and
Assoli18 [71]

Answer

The empirical formula is CrO₂Cl₂

Explanation:

Empirical formula is the simplest whole number ratio of an atom present in a compound.

The compound contain, Chromium=33.6%

                                         Chlorine=45.8%

                                          Oxygen=20.6%

And the molar mass of Chromium(Cr)=51.996 g mol.

                 Chlorine containing molar mass (Cl)= 35.45    g mol.

                 Oxygen containing molar mass (O)=15.999  g mol.

Step-1

 Then,we will get,

Cr=\frac{1}{51.996} \times33.6=0.64 mol

Cl= \frac{1}{35.45} \times45.8=1.29 mol.

O=\frac{1}{15.99} \times=1.28 mol.

Step-2

Divide the mole value with the smallest number of mole, we will get,

Cr= \frac{0.64}{0.64} =1

Cl= \frac{1.29}{0.64} =2

O= \frac{1.28}{0.64} =2

Then, the empirical formula of the compound is CrO₂Cl₂ (Chromyl chloride)

4 0
4 years ago
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3241004551 [841]

Answer:

The answer would be A

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5 0
3 years ago
Determine the resulting pH when 12mL if 0.16M HCl are reacted with 32 mL if 0.24M KOH.
TEA [102]

Answer:

pH = 13.1

Explanation:

Hello there!

In this case, according to the given information, we can set up the following equation:

HCl+KOH\rightarrow KCl+H_2O

Thus, since there is 1:1 mole ratio of HCl to KOH, we can find the reacting moles as follows:

n_{HCl}=0.012L*0.16mol/L=0.00192mol\\\\n_{KOH}=0.032L*0.24mol/L=0.00768mol

Thus, since there are less moles of HCl, we calculate the remaining moles of KOH as follows:

n_{KOH}=0.00768mol-0.00192mol=0.00576mol

And the resulting concentration of KOH and OH ions as this is a strong base:

[KOH]=[OH^-]=\frac{0.00576mol}{0.012L+0.032L}=0.131M

And the resulting pH is:

pH=14+log(0.131)\\\\pH=13.1

Regards!

3 0
3 years ago
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