The balanced chemical reaction is written as:
P4 + 10Cl2 = 4PCl5
To determine the moles of PCl5 produced, we use the initial amount of the limiting reactant which is P4 and the relation from the reaction. We do as follows:
22.0 g P4 ( 1 mol / 123.90 g ) ( 4 mol PCl5 / 1 mol P4 ) = 0.7103 mol PCl5 produced
a) First, to get ΔG°rxn we have to use this formula when:
ΔG° = - RT ㏑ K
when ΔG° is Gibbs free energy
and R is the constant = 8.314 J/mol K
and T is the temperature in Kelvin = 25 °C+ 273 = 298 K
and when K = 4.4 x 10^-2
so, by substitution:
ΔG°= - 8.314 * 298 *㏑(4.4 x 10^-2)
= -7739 J = -7.7 KJ
b) then, to get E° cell for a redox reaction we have to use this formula:
ΔE° Cell = (RT / nF) ㏑K
when R is a constant = 8.314 J/molK
and T is the temperature in Kelvin = 25°C + 273 = 298 K
and n = no.of moles of e- from the balanced redox reaction= 3
and F is Faraday constant = 96485 C/mol
and K = 4.4 x 10^-2
so, by substitution:
∴ ΔE° cell = (8.314 * 298 / 3* 96485) *㏑(4.4 x 10^-2)
= - 2.7 x 10^-2 V
Answer:
The correct answer is - 29.45 / 100 x 25.6 = 7.5392 grams
Explanation:
It is given in the question that in 100 gms of CaSO4 there are 29.45 grams of Ca present and there is 25.6 gram of total CaSO4 sample present, So, to calculate the exact value of calcium in this given sample is:
mass of Ca = total amount of sample*percentage of calcium in sample /100
M of Ca =25.6*29.45/100
M of Ca = 7.5392 grams
Thus, the correct procedure is given by 29.45 / 100 x 25.6 = 7.5392 grams
When electrons are filling energy levels, the lowest energy sublevels are occupied first. This is Hund's rule.
Hund's rules state that:
Every orbital in a sublevel has to be singularly occupied before any other orbital is able to be doubly occupied.
All of the electrons in single occupied orbitals have to have the same spin to maximize the total spin.
The answer should be B: -3
