Answer:
The rate law for second order unimolecular irreversible reaction is
![\frac{1}{[A]} = k.t + \frac{1}{[A]_{0} }](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%20k.t%20%2B%20%5Cfrac%7B1%7D%7B%5BA%5D_%7B0%7D%20%7D)
Explanation:
A second order unimolecular irreversible reaction is
2A → B
Thus the rate of the reaction is
![v = -\frac{1}{2}.\frac{d[A]}{dt} = k.[A]^{2}](https://tex.z-dn.net/?f=v%20%3D%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%20%3D%20k.%5BA%5D%5E%7B2%7D)
rearranging the ecuation
![-\frac{1}{2}.\frac{k}{dt} = \frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%20%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Integrating between times 0 to <em>t </em>and between the concentrations of ![[A]_{0}](https://tex.z-dn.net/?f=%5BA%5D_%7B0%7D)
to <em>[A].</em>
![\int\limits^0_t -\frac{1}{2}.\frac{k}{dt} =\int\limits^A_{0} _A\frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=%5Cint%5Climits%5E0_t%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%5Cint%5Climits%5EA_%7B0%7D%20_A%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Solving the integral
Answer:
Ethanol is completely miscible due to <u><em>presence</em></u> of Hydrogen bonding.
Ethanethiol is partially miscible due to <u><em>absence</em></u> of Hydrogen Bonding.
Explanation:
The miscibility of liquids depend upon the intermolecular interactions between the two liquids. The stronger the intermolecular interactions the more miscible will be the liquids.
Among the two given examples, Ethanol is more miscible in water because it exhibits hydrogen bonding which is considered the strongest intermolecular interaction. Hydrogen bonding occurs when the hydrogen atom is bonded to more electronegative atoms like Fluorine, Oxygen and Nitrogen. In this way the hydrogen atom gets partial positive charge and the electronegative atom gets partial negative charge. Hence, these partial charges results in attracting the opposite charges on other surrounding atoms.
While, in case of Ethanethiol the hydrogen atom is not bonded to any high electronegative atom hence, there will be no hydrogen bonding and therefore, there will be less interactions between the neighbour atoms.
Answer:
exosphere and ionosphere.
Explanation:
very high up,the earth's atmosphere becomes very thin. the region where atoms and moleculesescape into space is referred to as the exosphere. exosphere is on top of the thermosphere.
scientists what is called the ionospherean extension of the thermosphere. so technically, ionosphere is not another atmospheric layer.
E represents units of energy, m represents units of mass, and c2 is the speed of light squared, or multiplied by itself
So I THINK that A is the right answer but i may be wrong.
I hope this helped :)
