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ArbitrLikvidat [17]
3 years ago
10

What is the molarity of NaOH if 83.5 mL of NaOH is needed to react with 35.0mL of a 0.275 M solution of H2SO4?

Chemistry
1 answer:
Lostsunrise [7]3 years ago
7 0

Answer:

0.231 mol/L

Explanation:

The first step is to write the balanced equation for this reaction:

H_{2}SO_{4} +2NaOH ===> Na_{2}SO_{4}  +2H_{2}O

The second step is to find the number of moles in the acid:

number of moles = volume * concentration

                             = 0.035 L * 0.275 mol/L

                             = 0.009625 mol

The third step is to use the molar ratio from the balanced chemical equation to find the number of moles of NaOH that can neutralize 0.009625 mol of sulphuric acid.

n(sulphuric acid) : n(sodium hydroxide)

          1                :                   2

0.009625 mol    :                   x

x =  0.01925 mol

Fourth step is to calculate the concentration of sodium hydroxide:

concentration = \frac{number of moles}{volume} = \frac{0.01925}{0.0835} =0.231 mol/L

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Explanation:

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So, we need to break the bonds of liquid substance in order to convert it into vapor state. And, energy is absorbed for breaking of bonds which means that evaporation is an endothermic process.

Hence, the statement evaporation of water is an exothermic process is false.

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A combustion reaction will always release heat energy. Hence, combustion reaction is exothermic in nature.

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Hence, for an exothermic process value of \Delta H is negative.

Thus, we can conclude that statements which are true are as follows.

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3 years ago
7.00 of Compound x with molecular formula C3H4 are burned in a constant-pressure calorimeter containing 35.00kg of water at 25c.
beks73 [17]

Answer:

\Delta H_{f,C_3H_4}=276.8kJ/mol

Explanation:

Hello!

In this case, since the equation we use to model the heat exchange into the calorimeter and compute the heat of reaction is:

\Delta H_{rxn} =- m_wC_w\Delta T

We plug in the mass of water, temperature change and specific heat to obtain:

\Delta H_{rxn} =- (35000g)(4.184\frac{J}{g\°C} )(2.316\°C)\\\\\Delta H_{rxn}=-339.16kJ

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C_3H_4+4O_2\rightarrow 3CO_2+2H_2O

Whose enthalpy change involves the enthalpies of formation of propyne, carbon dioxide and water, considering that of propyne is the target:

\Delta H_{rxn}=3\Delta H_{f,CO_2}+2\Delta H_{f,H_2O}-\Delta H_{f,C_3H_4}

However, the enthalpy of reaction should be expressed in kJ per moles of C3H4, so we divide by the appropriate moles in 7.00 g of this compound:

\Delta H_{rxn} =-339.16kJ*\frac{1}{7.00g}*\frac{40.06g}{1mol}=-1940.9kJ/mol

Now, we solve for the enthalpy of formation of C3H4 as shown below:

\Delta H_{f,C_3H_4}=3\Delta H_{f,CO_2}+2\Delta H_{f,H_2O}-\Delta H_{rxn}

So we plug in to obtain (enthalpies of formation of CO2 and H2O are found on NIST data base):

\Delta H_{f,C_3H_4}=3(-393.5kJ/mol)+2(-241.8kJ/mol)-(-1940.9kJ/mol)\\\\\Delta H_{f,C_3H_4}=276.8kJ/mol

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