Answer:
The balanced chemical equation:
Heat of combustion per gram of phenol is 32.454 kJ/g
Heat of combustion per gram of phenol is 3,050 kJ/mol
Explanation:
Heat capacity of calorimeter = C = 11.66 kJ/°C
Initial temperature of the calorimeter = 
Final temperature of the calorimeter = 
Heat absorbed by calorimeter = Q
Heat released during reaction = Q'
Q' = -Q ( law of conservation of energy)
Energy released on combustion of 1.800 grams of phenol = Q' = -(58.4166 kJ)
Heat of combustion per gram of phenol:
Molar mass of phenol = 94 g/mol
Heat of combustion per gram of phenol:
Answer:
a) The equilibrium will shift in the right direction.
b) The new equilibrium concentrations after reestablishment of the equilibrium :
![[SbCl_5]=(0.370-x) M=(0.370-0.0233) M=0.3467 M](https://tex.z-dn.net/?f=%5BSbCl_5%5D%3D%280.370-x%29%20M%3D%280.370-0.0233%29%20M%3D0.3467%20M)
![[SbCl_3]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BSbCl_3%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
![[Cl_2]=(6.98\times 10^{-2}+x) M=(6.98\times 10^{-2}+0.0233) M=0.0931 M](https://tex.z-dn.net/?f=%5BCl_2%5D%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2Bx%29%20M%3D%286.98%5Ctimes%2010%5E%7B-2%7D%2B0.0233%29%20M%3D0.0931%20M)
Explanation:
a) Any change in the equilibrium is studied on the basis of Le-Chatelier's principle.
This principle states that if there is any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.
On increase in amount of reactant
If the reactant is increased, according to the Le-Chatlier's principle, the equilibrium will shift in the direction where more product formation is taking place. As the number of moles of 
is increasing .So, the equilibrium will shift in the right direction.
b)
Concentration of = 0.195 M
Concentration of 
= 
Concentration of 
=
On adding more 
to 0.370 M at equilibrium :
Initially
0.370 M 
At equilibrium:
(0.370-x)M 
The equilibrium constant of the reaction = 
The equilibrium expression is given as:
![K_c=\frac{[SbCl_3][Cl_2]}{[SbCl_5]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BSbCl_3%5D%5BCl_2%5D%7D%7B%5BSbCl_5%5D%7D)
On solving for x:
x = 0.0233 M
The new equilibrium concentrations after reestablishment of the equilibrium :
The reaction is
CaC₂(s) + 2H₂O (l) -----> Ca(OH)₂ (s) + C₂H₂ (g)
As we have data of gas ethyne (or acetylene), C₂H₂
We can calculate the moles of acetylene and from this we can estimate the mass of calcium carbide taken
the moles of acetylene will be calculated using ideal gas equation
PV =nRT
R = gas constant = 0.0821 Latm/molK
T = 385 K
V = volume = 550 L
P = Pressure = 1.25 atm
n = moles = ?
n = PV /RT = 1.25 X 550 / 0.0821 X 385 = 21.75 mol
As per balanced equation these moles of acetylene will be obtained from same moles of calcium carbide
moles of calcium carbide = 21.75mol
molar mass of CaC₂ = 40 + 24 = 64
mass of CaC₂ = moles X molar mass = 21.75 X 64 = 1392g
Answer:
Molecular mass is the amount of mass associated with a molecule. It is also called as molecular weight. It can be calculated by adding the mass of each atom multiplied by the number of atoms of the element present in the molecule. For example, water is made up of 2 hydrogen atoms and 1 oxygen atom.
Explanation:
