1-pentyne consists of a carbon chain of 5 carbons one with a triple bond. 1-octyne is a carbon chain of 8 carbons with a triple bond at some point. It is known that the longer the carbon chain the higher the boiling point since more energy will be required to break the bonds between carbons. Based on this it is predicted that 1-octyne will have a higher boiling point than 1-pentyne.
