Answer:
(a)

(b)

Explanation:
Hello,
(a) In this case, as the reaction is second-ordered, one uses the following kinetic equation to compute the concentration of NOBr after 22 seconds:
![\frac{1}{[NOBr]}=kt +\frac{1}{[NOBr]_0}\\\frac{1}{[NOBr]}=\frac{0.8}{M*s}*22s+\frac{1}{0.086M}=\frac{29.3}{M}\\](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BNOBr%5D%7D%3Dkt%20%2B%5Cfrac%7B1%7D%7B%5BNOBr%5D_0%7D%5C%5C%5Cfrac%7B1%7D%7B%5BNOBr%5D%7D%3D%5Cfrac%7B0.8%7D%7BM%2As%7D%2A22s%2B%5Cfrac%7B1%7D%7B0.086M%7D%3D%5Cfrac%7B29.3%7D%7BM%7D%5C%5C)
![[NOBr]=\frac{1}{29.2/M}=0.0342M](https://tex.z-dn.net/?f=%5BNOBr%5D%3D%5Cfrac%7B1%7D%7B29.2%2FM%7D%3D0.0342M)
(b) Now, for a second-order reaction, the half-life is computed as shown below:
![t_{1/2}=\frac{1}{k[NOBr]_0}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B1%7D%7Bk%5BNOBr%5D_0%7D)
Therefore, for the given initial concentrations one obtains:

Best regards.
Periodic table<span> of the </span>elements, in chemistry, the organized<span> array of all the chemical </span>elements<span> in order of increasing atomic number—i.e., the total number of protons in the atomic nucleus.</span>
Hey there!
Volume in mL :
1.25 * 1000 => 1250 mL
Density = 0.921 g/mL
Therefore:
Mass = density * volume
Mass = 0.921 * 1250
Mass = 1151.25 g