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Harlamova29_29 [7]
3 years ago
14

Arrange these molecules in order of decreasing mass: C​6​H​14​ , NO​2​ , Fe​2​O​3 ​, and CaCO​

Chemistry
1 answer:
babunello [35]3 years ago
6 0

The following is the arrangement of the given molecules in decreasing order of mass: \text{ Fe2O3} > \text{C6H14} > \text{CaCO} > \text{NO2}

<u>Solution:</u>

First inorder to arrange the elements in descending order of their mass we have to calculate the molecular mass of each element. The calculation is as follows:

<u>Mass of C6H14:</u>

C\rightarrow6\times12.01 = 72.06

H\rightarrow14\times1.008 = 14.112

<em>Mass of C6H14 is 86.172</em>

<u>Mass of NO2:</u>

N\rightarrow1\times14.0067 = 14.0067

O\rightarrow2\times15.9994 = 31.9988

<em>Mass of NO2 is 46.0055</em>

<u>Mass of Fe​2​O3:</u>

Fe\rightarrow2\times55.845 = 111.69

O\rightarrow3\times15.9994 = 47.9982

<em>Mass of Fe2O3 is 159.6882</em>

<u>Mass of CaCO:</u>

Ca\rightarrow1\times40.078 = 40.078

C\rightarrow1\times12.01 = 12.01

O\rightarrow1\times15.9994 = 15.9994

<em>Mass of CaCO will be 68.0874</em>

So, the order will be 159.6882>86.172>68.0874>46.0055 which is \text{ Fe2O3} > \text{C6H14} > \text{CaCO} > \text{NO2}

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Combine the two half-reactions that give the spontaneous cell reaction with the smallest E∘. Fe2+(aq)+2e−→Fe(s) E∘=−0.45V I2(s)+
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<u>Answer:</u> The spontaneous cell reaction having smallest E^o is I_2+Cu\rightarrow Cu^{2+}+2I^-

<u>Explanation:</u>

We are given:

E^o_{(Fe^{2+}/Fe)}=-0.45V\\E^o_{(I_2/I^-)}=0.54V\\E^o_{(Cu^{2+}/Cu)}=0.34V

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction. Here, iodine will always undergo reduction reaction, then copper and then iron.

The equation used to calculate electrode potential of the cell is:

E^o_{cell}=E^o_{oxidation}+E^o_{reduction}

The combination of the cell reactions follows:

  • <u>Case 1:</u>

Here, iodine is getting reduced and iron is getting oxidized.

The cell equation follows:

I_2(s)+Fe(s)\rightarrow Fe^{2+}(aq.)+2I^-(aq.)

Oxidation half reaction:  Fe(s)\rightarrow Fe^{2+}(aq.)+2e^-   E^o_{oxidation}=0.45V

Reduction half reaction:  I_2(s)+2e^-\rightarrow 2I_-(aq.)   E^o_{reduction}=0.54V

E^o_{cell}=0.45+0.54=0.99V

Thus, this cell will not give the spontaneous cell reaction with smallest E^o_{cell}

  • <u>Case 2:</u>

Here, iodine is getting reduced and copper is getting oxidized.

The cell equation follows:

I_2(s)+Cu(s)\rightarrow Cu^{2+}(aq.)+2I^-(aq.)

Oxidation half reaction:  Cu(s)\rightarrow Cu^{2+}(aq.)+2e^-   E^o_{oxidation}=-0.34V

Reduction half reaction: I_2(s)+2e^-\rightarrow 2I_-(aq.)   E^o_{reduction}=0.54V

E^o_{cell}=-0.34+0.54=0.20V

Thus, this cell will give the spontaneous cell reaction with smallest E^o_{cell}

  • <u>Case 3:</u>

Here, copper is getting reduced and iron is getting oxidized.

The cell equation follows:

Cu^{2+}(aq.)+Fe(s)\rightarrow Fe^{2+}(aq.)+Cu(s)

Oxidation half reaction:  Fe(s)\rightarrow Fe^{2+}(aq.)+2e^-   E^o_{oxidation}=0.45V

Reduction half reaction:  Cu^{2+}(aq.)+2e^-\rightarrow Cu(s)   E^o_{reduction}=0.34V

E^o_{cell}=0.45+0.34=0.79V

Thus, this cell will not give the spontaneous cell reaction with smallest E^o_{cell}

Hence, the spontaneous cell reaction having smallest E^o is I_2+Cu\rightarrow Cu^{2+}+2I^-

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