Answer: The order with respect to 
is 1.
Explanation:
Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
![Rate=k[NH_4^+]^x[NO_2^-]^y](https://tex.z-dn.net/?f=Rate%3Dk%5BNH_4%5E%2B%5D%5Ex%5BNO_2%5E-%5D%5Ey)
k= rate constant
x = order with respect to
y = order with respect to A
n = x+y = Total order
From trial 1: ![3.2\times 10^{-3}=k[0.0100]^x[0.200]^y](https://tex.z-dn.net/?f=3.2%5Ctimes%2010%5E%7B-3%7D%3Dk%5B0.0100%5D%5Ex%5B0.200%5D%5Ey)
(1)
From trial 2: ![6.4\times 10^{-3}=k[0.0200]^x[0.200]^y](https://tex.z-dn.net/?f=6.4%5Ctimes%2010%5E%7B-3%7D%3Dk%5B0.0200%5D%5Ex%5B0.200%5D%5Ey)
(2)
Dividing 2 by 1 :![\frac{6.4\times 10^{-3}}{3.2\times 10^{-3}}=\frac{k[0.0100]^x[0.2000]^y}{k[0.0200]^x[0.200]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B6.4%5Ctimes%2010%5E%7B-3%7D%7D%7B3.2%5Ctimes%2010%5E%7B-3%7D%7D%3D%5Cfrac%7Bk%5B0.0100%5D%5Ex%5B0.2000%5D%5Ey%7D%7Bk%5B0.0200%5D%5Ex%5B0.200%5D%5Ey%7D)
therefore x= 1
Thus order with respect to is 1.
Answer:
70 mL of 5% HCl and 30 mL of 15% HCl
Explanation:
We will designate x to be the fraction of the final solution that is composed of 5% HCl, and y to be the fraction of the final solution that is composed of 15% HCl. Since the percentage of the final solution is 8%, we can write the following expression:
5x + 15y = 8
Since x and y are fractions of a total, they must equal one:
x + y = 1
This is a system of two equations with two unknowns. We will proceed to solve for x. First, an expression for y is found:
y = 1 - x
This expression is substituted into the first equation and we solve for x.
5x + 15(1 - x) = 8
5x+ 15 - 15x = 8
-10x = -7
x = 7/10 = 0.7
We then calculate the value of y:
y = 1 - x = 1 - 0.7 = 0.3
Thus 0.7 of the 100 mL will be the 5% HCl solution, so the volume of 5% HCl we need is:
(100 mL)(0.7) = 70 mL
Similarly, the volume of 15% HCl we need is:
(100 mL)(0.3) = 30 mL
Answer:
That would be helium, with a melting point of 0.95 K (-272.20 °C)—although this happens only under considerable pressure (~25 atmospheres). At ordinary pressure, helium would remain liquid even if it could be chilled to absolute zero.
