1. The effect of a catalyst on a chemical reaction is to
2 answers:
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Answer:
Explanation:
According to the boiling point elevation law described by the equation , the increase in boiling point is directly proportional to the van 't Hoff factor.
The van 't Hoff factor for nonelectrolytes is 1, while for ionic substances, it is equal to the number of moles of ions produced when 1 mole of salt dissolves.
would produce 2 moles of ions per 1 mole of dissolved substance, sodium and bromide ions.
is insoluble in water, so it would barely dissociate and wouldn't practically change the boiling point.
would dissociate into 3 moles of ions per 1 mole of substance, two potassium cations and one sulfide anion.
is a gas, it would form some amount of carbonic acid when dissolved, however, carbonic acid is molecular and would yield i value of i = 1.
Therefore, potassium sulfide would raise a liquid's boiling point the most if all concentrations are equal.
Answer:
p-fluoronitrobenzene and sodium phenoxide is more appropriate
Explanation:
An ipso substitution is required to form p-nitrophenyl phenyl ether.
For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.
p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.
p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.
So, p-fluoronitrobenzene and sodium phenoxide is more appropriate
