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Activation energy is a thermodynamic barrier that must be overcome before products are formed in a reaction. It is the minimum amount of energy needed for a reaction to occur. The energy can be in the form of kinetic or potential energy. This concept was introduced by Svante Arrhenius, which brought about the Arrhenius equation which is a formula used to determine rate of reactions.
The boiling points need to differ by 50 degrees to enable their complete separation ie of two different liquids. The separation occurs by first evaporation of one of the liquids and then its condensation and collection. It is a physical process not a chemical one.
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