Saturated Solution: A solution with solute that dissolves until it is unable to dissolve anymore, leaving the undissolved substances at the bottom. Unsaturated Solution: A solution ( with less solute than the saturated solution )that completely dissolves, leaving no remaining substances. Supersaturated Solution.
Answer : The correct answer for a) 4-bromo-2-iodo-4-methyl pentane and b)5-bromo-2-ethoxy-2-methyl pentane.
A) Reaction with NaI :
Reaction of alkyl halide with NaI is known as Finkelstein Reaction . The acetone is used as solvent . It involves bimolecular nucleophillic substitution rmechanism (SN²) . There is replecement of one halogen with other occurs .
The incoming Nucleophile(Nu⁻) (halide) attacks on carbon from back side , while the leaving group (halide) leaves the compound from front side , simultaneously. The product so formed have is inverted .(Image)
NaI releases I⁻ ion which act as nucelophile and attacks on C1 carbon and Br⁻ from C1 carbon is released . Out of two bromines at C1 and C4 carbons , C1 is primary carbon which is less sterically hindered while C-4 is tertiary carbon and sterically hindered . So it is easy for incoming Nu⁻ to attack on C1 carbon .So Br⁻ is repleaced by I⁻.
1,4-dibromo-4-methylpentane + NaI → 4-bromo-1-iodo-4-methylpentane
The product formed from reaction between 1,4-dibromo-4-methylpentane and NaI is 4-bromo-1-iodo-4-methylpentane . (Image)
B) Reaction with AgNO3 :
Reaction of alkyl halide with AgNO3 in ethanol takes place via SN¹ ( unimolecular nucleophilic substitution ) mechanism . In this leaving group(halide) leaves from alkyl halide forming an intermediate carbocation species . The incoming Nu⁻ attack on this carbocation.
AgNO3 reacts releases Ag⁺ion which abstract Br⁻ of C-4 carbon from 1,4-dibromo-4-methylpentane. THis forms tertiary carbocation which is more stable than carbocation formed by removal of Br from C-1 . The ethanol being more Nucleophilic than NO₃⁻ (from AgNO₃), attacks on this carbocation .(Image )
The product formed as a result is 5-bromo-2-ethoxy-2-methyl pentane.
1/16 ( ignore this the stupid website just makes us use 20 characters UGH! )
The mass of reacted magnesium chloride is 23.75g, percent by mass of solution magnesium chloride is 90.9%.
<h3>What is the relation between mass & moles?</h3>
Relation between the mass and moles of any substance will be represented as:
n = W/M, where
- W = given mass
- M = molar mass
Moles of MgCl₂ = 200g / 95g/mol = 2.1mol
Moles of NaOH = 20g / 0.5mol
Given chemical reaction is:
MgCl₂ + 2NaOH → 2NaCl + Mg(OH)₂
From the stoichiometry of the reaction it is clear that
- 1 mole of MgCl₂ = reacts with 2 moles of NaOH
- 0.5 mole of NaOH = reacts with (1/2)(0.5)=0.25 moles of MgCl₂
Mass of reacted MgCl₂ = (0.25mol)(95g/mol) = 23.75g
Percent by mass of MgCl₂ in the given solution mixture will be calculated as:
- % by mass = (Mass of MgCl₂ / Total mass of mixture) × 100%
- Percent by mass of MgCl₂ = (200/200+20)×100% = 90.0&
In the above reaction we obtain NaCl as a solid, and MgCl₂ is the limiting reagent in it, from which 2 moles of NaCl is produced means
- 0.25 moles of MgCl₂ = produces 0.5 moles of NaCl
Mass of NaCl = (0.5mol)(58.5g/mol) = 29.25g
Hence, mass of reacted MgCl₂ is 23.75g, percent by mass of solution magnesium chloride is 90.9% and mass of the obtained solid is 29.25g.
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Answer:
El volumen final del sistema es 1.2L
Explanation:
La ley de Charles establece que el incremento de la temperatura de un gas produce un incremento en el volumen directamente proporcional cuando la presión permanece constante. La ecuación es:
V₁/T₁ = V₂/T₂
<em>Donde V es volumen y T temperatura absoluta de un gas en 1, el estado inicial y 2, su estado final.</em>
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Reemplazando:
V₁ = 1.3L
T₁ = 50°C + 273.15K = 323.15K
V₂ = Incógnita
T₂ = 300K
1.3L/323.15K = V₂/300K
1.2L = V₂
<h3>El volumen final del sistema es 1.2L</h3>
