Carbonyl compounds can be protonated on the carbonyl oxygen. Protonation of the carbonyl oxygen gives a species whose positive c
harge is delocalized by resonance. Explain why acetic acid (ethanoic acid) is more readily protonated than acetone (propanone).
1 answer:
Answer:
Full explanation is given below.
Explanation:
Positive charge on carbonyl oxygen atom in protonated acetic acid is delocalized by stronger electron donating resonating effect of lone pair of oxygen atom in adjacent -OH group.
Positive charge on carbonyl oxygen atom in protonated acetone is delocalized by weaker electron donating inductive effect of two adjacent methyl groups.
Higher the delocalization of positive charge, higher will be stability of protonated species. Hence acetic acid is more rapidly protonated.
Resonance structures of protonated acetic acid has been shown below.
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Answer:
66.67%
Explanation:
From the given information:
mass of cyclohexane = 2.9949 grams
density of cyclohexane = 0.779 g/mL
Recall that:
Density = mass/volume
∴
Volume = mass/density
So, the volume of cyclohexane = 2.9949 g/ 0.779 g/mL
= 3.8445 mL
Also,
mass of propylbenzene = 1.6575 grams
density of propylbenzene = 0.862 g/mL
Volume of propylbenzene = 1.6575 g/ 0.862 g/mL
= 1.9229 mL
The volume % composition of cyclohexane from the mixture is:
= 66.67%