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Dmitriy789 [7]
3 years ago
8

Rank these species by their ability to act as an oxidizing agent. cu+ mg2+ fe2+

Chemistry
1 answer:
natita [175]3 years ago
7 0

Explanation:

The species or elements which gain electrons and reduces itself are known as oxidizing agent or oxidant.

Ability of an element to act as an oxidizing agent depends on its electrode potential.

The electrode potential of Cu^{+} is 0.52 V.

The electrode potential of Fe^2+ is -0.41 V.

The electrode potential of Mg^{2+} is -2.38 V.

Greater is the value of electrode potential, stronger will be the oxidizing agent.

Therefore, rank of these species by their ability to act as an oxidizing agent are as follows.

       Cu^{+} > Fe^2+ > Mg^{2+}

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Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th
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pH = 13.5

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}

The mixture would contain

  • 0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol} of \text{OH}^{-} and
  • 0.1 \times 0.5 = 0.05 \; \text{mol} of \text{Ac}^{-}

if \text{Ac}^{-} undergoes no hydrolysis; the solution is of volume 0.1 + 0.4 = 0.5 \; \text{L} after the mixing. The two species would thus be of concentration 0.30 \; \text{mol} \cdot \text{L}^{-1} and 0.10 \; \text{mol} \cdot \text{L}^{-1}, respectively.

Construct a RICE table for the hydrolysis of \text{Ac}^{-} under a basic aqueous environment (with a negligible hydronium concentration.)

\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}

The question supplied the <em>acid</em> dissociation constant pK_afor acetic acid \text{HAc}; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant pK_b for its conjugate base, \text{Ac}^{-}. The following relationship relates the two quantities:

pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})

... where the water self-ionization constant pK_w \approx 14 under standard conditions. Thus pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3. By the definition of pK_b:

[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b =  10^{-pK_{b}}

x \cdot (0.3 + x) / (0.1 - x) = 10^{-9.3}

x = 1.67 \times 10^{-10} \; \text{M} \approx 0 \; \text{M}

[\text{OH}^{-}] = 0.30 +x \approx 0.30 \; \text{M}

pH = pK_{w} - pOH = 14 + \text{log}_{10}[\text{OH}^{-}] = 14 + \text{log}_{10}{0.30} = 13.5

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