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sineoko [7]
3 years ago
6

If the two atoms participating in a bond have an electron negativity difference of 1.9 , what type of of bond would they be part

icipating in ?
Chemistry
1 answer:
brilliants [131]3 years ago
7 0

Answer:

Polar covalent bond.

Explanation:

When the bond is formed between the atoms by sharing the electrons the bond thus have covalent character.   The atom with larger electronegativity attract the electron pair more towards it self and becomes partial negative while the other atom becomes partial positive.  When the electronegativity difference is less than 0.4 the bond is non polar covalent.

When bonded atoms have greater electronegativity difference i.e 2 or greater than two the bond is ionic because electron is transfer from low electronegative atom to highest electronegative atom.

For example:

In water the electronegativity of oxygen is 3.44 and hydrogen is 2.2. That's why electron pair attracted more towards oxygen, thus oxygen becomes partial negative and hydrogen becomes partial positive.

In case of H₂, Cl₂, Br₂ the bond has very high covalent character because of zero electronegativity difference.

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2 years ago
Given K = 3.61 at 45°C for the reaction A(g) + B(g) equilibrium reaction arrow C(g) and K = 7.19 at 45°C for the reaction 2 A(g)
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Answer:

K = 0.55

Kp = 0.55

mol fraction B = 0.27

Explanation:

We need to calculate the equilibrium constant for the reaction:

C(g) + D(g) ⇄ 2B(g)              K₁= ?                       (1)

and we are given the following equilibria with their respective Ks

A(g) + B(g) ⇄ C(g)                 K₂= 3.61                 (2)

2 A(g) + D(g)  ⇄ C(g)             K₃= 7.19                 (3)

all at 45 ºC.

What we need to do to solve this question is to manipulate equations (2) and (3)  algebraically  to get our desired equilibrium (1).

We are allowed to reverse  reactions, in that case we take the reciprocal of K as our new K' ; we can also  add two equilibria together, and the new equilibrium constant will be the product of their respective Ks .

Finally if we multiply by a number then we raise the old constant to that factor to get the new equilibrium constant.

With all this  in mind, lets try to solve our question.

Notice A is not in our goal equilibrium (3)  and we want D as a reactant . That  suggests we should reverse the first equilibria and multiply it by two since we have 2 moles of B  as product in our  equilibrium (1) . Finally we would add (2) and (3) to get  (1) which is our final  goal.

2C(g)             ⇄  2A(g) + 2B(g)  K₂´= ( 1/ 3.61 )²  

                                   ₊

2 A(g) + D(g)  ⇄     C(g)               K₃ = 7.19  

<u>                                                                                    </u>

C(g) + D(g)     ⇄    2B(g)       K₁ = ( 1/ 3.61 )²   x  7.19

                                             K₁ = 0.55

Kp is the same as K = 0.55 since the equilibrium constant expression only involves  gases.

To compute the last part lets setup the following mnemonic  ICE table to determine the quantities at equilibrium:

pressure (atm)        C             D           B

initial                     1.64          1.64         0

change                    -x             -x        +2x

equilibrium          1.64-x         1.64-       2x

Thus since

Kp =0.55 = pB²/ (pC x pD) = (2x)²/ (1.64 -x)²  where p= partial pressure

Taking square root to both sides of the equation we have

√0.55 = 2x/(1.64 - x)

solving for x  we obtain a value of 0.44 atm.

Thus at equilibrium we have:

(1.64 - 0.44) atm = 1.20 atm = pC = p D

2(0.44) = 0.88 = pB

mole fraction of B = partial pressure of B divided into the total gas pressure:

X(B) = 0.88 / ( 1.20 + 1.20 + 0.88 ) = 0.27

8 0
3 years ago
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