Answer:
a. Rate = k×[A]
b. k = 0.213s⁻¹
Explanation:
a. When you are studying the kinetics of a reaction such as:
A + B → Products.
General rate law must be like:
Rate = k×[A]ᵃ[B]ᵇ
You must make experiments change initial concentrations of A and B trying to find k, a and b parameters.
If you see experiments 1 and 3, concentration of A is doubled and the Rate of the reaction is doubled to. That means a = 1
Rate = k×[A]¹[B]ᵇ
In experiment 1 and to the concentration of B change from 1.50M to 2.50M but rate maintains the same. That is only possible if b = 0. (The kinetics of the reaction is indepent to [B]
Rate = k×[A][B]⁰
<h3>Rate = k×[A]</h3>
b. Replacing with values of experiment 1 (You can do the same with experiment 3 obtaining the same) k is:
Rate = k×[A]
0.320M/s = k×[1.50M]
<h3>k = 0.213s⁻¹</h3>
The answer is 1.56L. Avogadro's Law states that the volume of a gas is directly proportional to the number of moles (or a number of particles) of gas when the temperature and pressure are held constant.
V∝n
V₁/n₁m= V₂/n₂
V₁ = initial volume of gas = 12.5 L
V₂ = final volume of gas = ?
n₁ = initial moles of gas = 0.016 mole
n₂ = final moles of gas = 0.016-0.007 = 0.002 mole
V₁/n₁m= V₂/n₂
V₂= 1.56L
Avogadro's Law is in evidence whenever you blow up a balloon. The volume of the balloon increases as you add moles of gas to the balloon by blowing it up.
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Before proceeding, we should write the reaction equation to better understand what is happening:
2AgNO₃ + Na₂S → Ag₂S + 2NaNO₃
Now, we may apply the law of conservation of mass, due to which the total mass before a chemical reaction is equivalent to the total mass after a chemical reaction. Therefore:
Mass of silver nitrate + mass of sodium sulfide = mass of silver sulfide + mass of sodium nitrate
Mass of silver nitrate + 156.2 = 595.8 + 340
Mass of silver nitrate = 779.6 grams
You can stop the burning of methane with water or carbon dioxide extinguishers but problems arise when you try to use this to stop the burning of the magnesium.
Explanation:
To burn magnesium (Mg) and methane (CH₄) you need to react them with oxygen:
2 Mg (s) + O₂ (g) → 2 MgO + heat
CH₄ (g) + 2 O₂ (g) → CO₂ (g) + 2 H₂O (g) + heat
However at that temperatures magnesium (Mg) is able to react with water (H₂O) and carbon dioxide (CO₂).
Mg (s) + 2 H₂O (l) → Mg(OH)₂ (s) + H₂ (g)
2 Mg (s) + CO₂ (g) → 2 MgO (s) + C (s)
So the safe option to stop the burning of the magnesium is to limit the oxygen in the air.
we have used the following notations:
(s) - solid
(g) - gas
(l) - liquid
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combustion reactions
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